Ultrafast charge transfer and vibronic coupling in a laser-excited hybrid inorganic/organic interface

M Jacobs, J Krumland, AM Valencia, H Wang… - … in Physics: X, 2020 - Taylor & Francis
Hybrid interfaces formed by inorganic semiconductors and organic molecules are intriguing
materials for opto-electronics. Interfacial charge transfer is primarily responsible for their …

Quantum modeling of ultrafast photoinduced charge separation

CA Rozzi, F Troiani, I Tavernelli - Journal of Physics: Condensed …, 2017 - iopscience.iop.org
Phenomena involving electron transfer are ubiquitous in nature, photosynthesis and
enzymes or protein activity being prominent examples. Their deep understanding thus …

Real-time TD-DFT with classical ion dynamics: Methodology and applications

G Kolesov, O Grånäs, R Hoyt… - Journal of Chemical …, 2016 - ACS Publications
We present a method for real-time propagation of electronic wave functions, within time-
dependent density functional theory (RT-TDDFT), coupled to ionic motion through mean …

Charge Separation in Donor–C60 Complexes with Real-Time Green Functions: The Importance of Nonlocal Correlations

EV Bostrom, A Mikkelsen, C Verdozzi, E Perfetto… - Nano …, 2018 - ACS Publications
We use the nonequilibrium Green function (NEGF) method to perform real-time simulations
of the ultrafast electron dynamics of photoexcited donor–C60 complexes modeled by a …

Structural Flexibility Slows Down Charge Transfers in Diaminoterephthalate-C60 Dyads

D Timmer, G Hergert, L Gerhards… - The Journal of …, 2024 - ACS Publications
In recent years, research has emphasized the significant influence of vibronic couplings on
charge separation in donor–acceptor molecules and thin films. Diaminoterephthalates …

Polarized local excitons assist charge dissociation in Y6-based nonfullerene organic solar cells: a nonadiabatic molecular dynamics study

B Liu, PCY Chow, J Liu, D Pan - Journal of Materials Chemistry A, 2024 - pubs.rsc.org
Y6-based nonfullerene organic solar cells (OSCs) have achieved an outstanding power
conversion efficiency (PCE) of over 19% due to the low energy loss and high exciton …

Orthogonally protected diaminoterephthalate scaffolds: installation of two functional units at the chromophore

L Buschbeck, J Christoffers - The Journal of Organic Chemistry, 2018 - ACS Publications
The 2, 5-diaminoterephthalate structural motif is a powerful chromophore with remarkable
fluorescence properties. Containing two carboxylate and two amino functions, it defines a …

Nonlinear light absorption in many-electron systems excited by an instantaneous electric field: a non-perturbative approach

A Guandalini, C Cocchi, S Pittalis, A Ruini… - Physical Chemistry …, 2021 - pubs.rsc.org
Applications of low-cost non-perturbative approaches in real time, such as time-dependent
density functional theory, for the study of nonlinear optical properties of large and complex …

A Diaminoterephthalate–C60 Dyad: A New Material for Optoelectronic Applications

L Freimuth, CA Rozzi, C Lienau, J Christoffers - Synthesis, 2015 - thieme-connect.com
Diaminoterephthalate was used for the first time as a chromophore in a dyad with [60]
fullerene. The synthesis was accomplished from the benzyl methyl diester by hydrogenolytic …

Diaminoterephthalate fluorescence dyes–versatile tools for life sciences and materials science

J Christoffers - European Journal of Organic Chemistry, 2018 - Wiley Online Library
The 2, 5‐diaminoterephthalate (DAT) structural motif is a powerful chromophore with
remarkable fluorescence properties. Containing two carboxylate and two amino groups, it …