Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Due to the heterometallic synergistic effects from different metals, heterometallic clusters are
of great importance in small-molecule activation and catalysis. For example, both biological …

Bimetallic catalysts of nickel (0) with a trivalent rare-earth ion or Ga (III), NiML3 (where L is
[iPr2PCH2NPh]−, and M is Sc, Y, La, Lu, or Ga), were investigated for the selective …

Cooperative chemistry between two or more metal centres can show enhanced reactivity
compared to the monometallic fragments. Given the paucity of actinide–metal bonds …

The coordination and organometallic chemistry of the f-elements, that is group 3, lanthanide,
and actinide ions, supported by nitrogen ligands, eg amides, imides, and nitrides, has …

Ligands are known to play a crucial role in the construction of complexes with metal–metal
bonds. Compared with metal–metal bonds involving d-block transition metals, knowledge of …

Sequential reactions of heptadentate phosphinoamine LH3 with rare-earth metal tris-alkyl
precursor (Me3SiCH2) 3Ln (THF) 2 (Ln= Sc, Lu, Yb, Y, Gd) and a low-valent cobalt complex …

Heterobi-and multimetallic complexes providing close proximity between several metal
centers serve as active species in artificial and enzymatic catalysis, and in model systems …

The field of heterobimetallic chemistry has rapidly expanded over the last decade. In
addition to their interesting structural features, heterobimetallic structures have been found …

Controlling the reactivity of transition metals using secondary, σ‐accepting ligands is an
active area of investigation that is impacting molecular catalysis. Herein we describe the …