Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration

W Huang, X Ma, O Sato, D Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …

Charge frustration in ligand design and functional group transfer

D Munz, K Meyer - Nature Reviews Chemistry, 2021 - nature.com
Molecules with different resonance structures of similar importance, such as
heterocumulenes and mesoionics, are prominent in many applications of chemistry …

Charge Delocalization and Bulk Electronic Conductivity in the Mixed-Valence Metal–Organic Framework Fe(1,2,3-triazolate)2(BF4)x

JG Park, ML Aubrey, J Oktawiec… - Journal of the …, 2018 - ACS Publications
Metal–organic frameworks are of interest for use in a variety of electrochemical and
electronic applications, although a detailed understanding of their charge transport …

Magnetic ordering through itinerant ferromagnetism in a metal–organic framework

JG Park, BA Collins, LE Darago, T Runčevski… - Nature Chemistry, 2021 - nature.com
Materials that combine magnetic order with other desirable physical attributes could find
transformative applications in spintronics, quantum sensing, low-density magnets and gas …

In situ characterization of cofacial Co(IV) centers in Co4O4 cubane: Modeling the high-valent active site in oxygen-evolving catalysts

CN Brodsky, RG Hadt, D Hayes… - Proceedings of the …, 2017 - National Acad Sciences
The Co4O4 cubane is a representative structural model of oxidic cobalt oxygen-evolving
catalysts (Co-OECs). The Co-OECs are active when residing at two oxidation levels above …

X-ray Spectroscopic Characterization of Co(IV) and Metal–Metal Interactions in Co4O4: Electronic Structure Contributions to the Formation of High-Valent States …

RG Hadt, D Hayes, CN Brodsky… - Journal of the …, 2016 - ACS Publications
The formation of high-valent states is a key factor in making highly active transition-metal-
based catalysts of the oxygen evolution reaction (OER). These high oxidation states will be …

Transition metal redox switches for reversible “on/off” and “slow/fast” single-molecule magnet behaviour in dysprosium and erbium bis-diamidoferrocene complexes

CM Dickie, AL Laughlin, JD Wofford… - Chemical …, 2017 - pubs.rsc.org
Single-molecule magnets (SMMs) are considered viable candidates for next-generation
data storage and quantum computing. Systems featuring switchability of their magnetization …

Amine-assisted exfoliation and electrical conductivity modulation toward few-layer FePS 3 nanosheets for efficient hydrogen evolution

Z Yu, J Peng, Y Liu, W Liu, H Liu, Y Guo - Journal of Materials …, 2019 - pubs.rsc.org
Layered metal phosphorus trichalcogenides (MPX3, M= transition metal, X= S or Se) have
been established as new efficient catalysts for water splitting, with FePS3 as one …

Best Practices and Protocols in Mössbauer Spectroscopy

F Grandjean, GJ Long - Chemistry of Materials, 2021 - ACS Publications
Over the past 50 years or so, the authors have written and reviewed many papers dealing
with Mössbauer spectral research and have noticed many pitfalls, omissions, and marginal …

Geometry-dependent valence tautomerism, magnetism, and electrical conductivity in 1D iron–tetraoxolene chains

AA Kamin, IP Moseley, J Oh, EJ Brannan… - Chemical …, 2023 - pubs.rsc.org
Redox-active tetraoxolene ligands such as 1, 4-dihydroxybenzoquinone provide access to a
diversity of metal–organic architectures, many of which display interesting magnetic …