Superexchange antiferromagnetism and cryogenic magnetocaloric effect in scheelite-type GdTi0. 5Mo0. 5O4 compound

J Gong, Z Mo, Y Wang, Z Li, L Zhang, Q Fu, Y Li… - Ceramics …, 2024 - Elsevier
Scheelite-type LnLiF 4 compounds have become promising cryogenic magnetic refrigerants
due to their giant low-field magnetocaloric effect (MCE). This work presents an example of a …

Exceptional Magnetocaloric Responses in a Gadolinium Silicate with Strongly Correlated Spin Disorder for Sub‐Kelvin Magnetic Cooling

ZW Yang, J Zhang, B Liu, X Zhang, D Lu… - Advanced …, 2024 - Wiley Online Library
The development of magnetocaloric materials with a significantly enhanced volumetric
cooling capability is highly desirable for the application of adiabatic demagnetization …

Magnetocaloric Properties in Rare-Earth-Based Metal–Organic Frameworks: Influence of Magnetic Density and Hydrostatic Pressure

RL Vasile, RS Silva Jr, E Céspedes… - Inorganic …, 2023 - ACS Publications
Magnetic refrigeration based on the magnetocaloric effect (MCE) in metal–organic
frameworks (MOF) is regarded as an attractive approach to create more sustainable cooling …

Continuous Spin Excitations in the Three-Dimensional Frustrated Magnet

W Yao, Q Huang, T Xie, A Podlesnyak, A Brassington… - Physical Review Letters, 2023 - APS
Continuous spin excitations are widely recognized as one of the hallmarks of novel spin
states in quantum magnets, such as quantum spin liquids (QSLs). Here, we report the …

Robust Spin Liquidity in 2D Metal‐Organic Framework Cu3 (HHTP)2 with S=1/2 Kagome Lattice

P Ninawe, A Jain, M Sangole, M Anas… - … A European Journal, 2024 - Wiley Online Library
On one hand electron or hole doping of quantum spin liquid (QSL) may unlock high‐
temperature superconductivity and on the other hand it can disrupt the spin liquidity, giving …

Magnetic order in the two-dimensional metal-organic framework manganese pyrazinecarboxylate with Mn-Mn dimers

S Calder, R Baral, N Narayanan, LD Sanjeewa - Physical Review Materials, 2023 - APS
The magnetic properties of [Mn (pyrazinecarboxylate) 2] n, empirical formula C 10 H 6 MnN
4 O 4, are investigated through susceptibility, heat capacity, and neutron scattering …

Towards frustration in Eu (II) Archimedean tessellations

H Chen, AS Manvell, M Kubus, MA Dunstan… - Chemical …, 2023 - pubs.rsc.org
Self-assembly of trans-{EuI2} nodes and ditopic ligands leads to isoreticular 2D frameworks
featuring a rare, non-kagome Archimedean tessellation. The topology and intra-layer Eu (II) …

Cs2Fe2(MoO4)3─A Strongly Frustrated Magnet with Orbital Degrees of Freedom and Magnetocaloric Properties

L Kubíčková, AK Weber, M Panthöfer… - Chemistry of …, 2024 - ACS Publications
We report an in-depth study of the thermodynamic and magnetocaloric properties of a
strongly frustrated magnet, Cs2Fe2 (MoO4) 3. The underlying structure belongs to the …

Frustration on a centered pyrochlore lattice in metal-organic frameworks

RP Nutakki, R Röß-Ohlenroth, D Volkmer, A Jesche… - Physical Review …, 2023 - APS
Geometric frustration inhibits magnetic systems from ordering, opening a window to
unconventional phases of matter. The paradigmatic frustrated lattice in three dimensions to …

Intertwining of Localized (d) and Delocalized (π) Spins in Magnetically Frustrated Two-Dimensional Metal–Organic Frameworks

A Ugale, P Ninawe, A Jain, M Sangole… - Inorganic …, 2024 - ACS Publications
Two-dimensional metal–organic frameworks (2D MOFs) are emerging as a new class of
multifunctional materials for diversified applications, although magnetic properties have not …