Ultrafast excited-state dynamics in nucleic acids
The scope of this review is the nature and dynamics of the singlet excited electronic states
created in nucleic acids and their constituents by UV light. Interest in the UV photochemistry …
created in nucleic acids and their constituents by UV light. Interest in the UV photochemistry …
Homogeneous organic reactions as mechanistic probes in supercritical fluids
JF Brennecke, JE Chateauneuf - Chemical Reviews, 1999 - osti.gov
An interesting and intriguing aspect of supercritical fluid solutions is their microscopic
inhomogeneities. The most well-known of these are the long-range densities fluctuations …
inhomogeneities. The most well-known of these are the long-range densities fluctuations …
DNA excited-state dynamics: Ultrafast internal conversion and vibrational cooling in a series of nucleosides
To better understand DNA photodamage, several nucleosides were studied by femtosecond
transient absorption spectroscopy. A 263-nm, 150-fs ultraviolet pump pulse excited each …
transient absorption spectroscopy. A 263-nm, 150-fs ultraviolet pump pulse excited each …
Ultrafast internal conversion of electronically excited RNA and DNA nucleosides in water
The DNA and RNA bases absorb ultraviolet (UV) light of wavelengths shorter than 300 nm
strongly, and are the dominant UV absorbers in many cells. 1 Not surprisingly, nature has …
strongly, and are the dominant UV absorbers in many cells. 1 Not surprisingly, nature has …
Cooling dynamics of an optically excited molecular probe in solution from femtosecond broadband transient absorption spectroscopy
SA Kovalenko, R Schanz, H Hennig… - The Journal of Chemical …, 2001 - pubs.aip.org
The cooling of p-nitroaniline (PNA), dimethylamino-p-nitroaniline (DPNA) and trans-stilbene
(t-stilbene) in solution is studied experimentally and theoretically. Using the pump …
(t-stilbene) in solution is studied experimentally and theoretically. Using the pump …
Femtosecond relaxation of photoexcited para-nitroaniline: solvation, charge transfer, internal conversion and cooling
SA Kovalenko, R Schanz, VM Farztdinov… - Chemical Physics …, 2000 - Elsevier
The ultrafast relaxation of p-nitroaniline (PNA) in water and acetonitrile is studied
experimentally and theoretically. Transient absorption spectra are measured by the pump …
experimentally and theoretically. Transient absorption spectra are measured by the pump …
Pressure and composition dependences of acetone laser-induced fluorescence with excitation at 248, 266, and 308 nm
MC Thurber, RK Hanson - Applied Physics B, 1999 - Springer
In previous studies, acetone has been successfully applied as a tracer for planar laser-
induced fluorescence (PLIF) measurements of concentration and temperature. The desire to …
induced fluorescence (PLIF) measurements of concentration and temperature. The desire to …
Early events in the photochemistry of aryl azides from femtosecond UV/Vis spectroscopy and quantum chemical calculations
G Burdzinski, JC Hackett, J Wang… - Journal of the …, 2006 - ACS Publications
The photochemistry of para-and ortho-biphenylyl azides and 1-naphthyl azide was studied
by ultrafast spectroscopy. In every case, the singlet azide second excited states were …
by ultrafast spectroscopy. In every case, the singlet azide second excited states were …
Connecting chemical dynamics in gases and liquids
CG Elles, FF Crim - Annu. Rev. Phys. Chem., 2006 - annualreviews.org
▪ Abstract Modern ultrafast spectroscopic techniques provide new opportunities to study
chemical reaction dynamics in liquids and hold the possibility of obtaining much of the same …
chemical reaction dynamics in liquids and hold the possibility of obtaining much of the same …
Solvent-dependent photophysics of 1-cyclohexyluracil: ultrafast branching in the initial bright state leads nonradiatively to the electronic ground state and a long-lived …
PM Hare, CE Crespo-Hernandez… - The Journal of Physical …, 2006 - ACS Publications
The modified nucleic acid base, 1-cyclohexyluracil, was studied by femtosecond transient
absorption spectroscopy in protic and aprotic solvents of varying polarity. UV excitation at …
absorption spectroscopy in protic and aprotic solvents of varying polarity. UV excitation at …