While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …

Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …

A series of dinitrogen-bridged dimolybdenum–dinitrogen complexes bearing metallocene-
substituted PNP-pincer ligands is synthesized by the reduction of the corresponding …

Abstract When Ziegler and Korav serendipitously prepared [Fe 2 (CO) 6 (μ-pdt)] in 1979 they
could not have anticipated that some 40 years later it would be a mainstay of attempts to …

Transition-metal hydride radical cations (TMHRCs) are involved in a variety of chemical and
biochemical reactions, making a more thorough understanding of their properties essential …

[FeFe]-Ase biomimics containing a redox-active ferrocenyl diphosphine have been prepared
and their ability to reduce protons and oxidise H2 studied, including 1, 1′-bis …

The field of proton reduction by iron complexes without thiolate bridging ligand (s) in
homogeneous systems is reviewed. Till date electrocatalytic proton reduction by iron …

Abstract Reaction of [Fe 2 (CO) 6 (μ-pdt)] with the small bite-angle diphosphine 2, 2′-bis
(diphenylphosphino) propane gave the chelated complex [Fe 2 (CO) 4 {κ 2-Ph 2 PC (Me 2) …

[FeFe]-hydrogenases contain strongly electronically coupled diiron [2Fe] H and tetrairon
[Fe4–S4] H clusters, and thus much recent effort has focused on the chemistry of diiron …