Strong circularly polarized luminescence at 1550 nm from enantiopure molecular erbium complexes
Circularly polarized luminescence (CPL) in two subregions of the near-infrared (NIR) has
been achieved. By leveraging the rigidity and diminishing detrimental vibrations of the …
been achieved. By leveraging the rigidity and diminishing detrimental vibrations of the …
High circularly polarized luminescence brightness from analogues of Shibasaki's lanthanide complexes
To reach the promising potential of circularly polarized luminescence (CPL) emitters, high
CPL brightness must be achieved. We describe the synthesis of analogues of the C3 …
CPL brightness must be achieved. We describe the synthesis of analogues of the C3 …
Expanding the rare-earth metal binolate catalytic multitool beyond enantioselective organic synthesis
Conspectus Shibasaki's rare earth alkali metal BINOLate (REMB) framework has provided
chemists with a general catalyst platform to access a range of enantioenriched small …
chemists with a general catalyst platform to access a range of enantioenriched small …
Coordination Modes and Binding Patterns in Lanthanum Phosphoramide Complexes
A monoanionic phosphoramide ligand is introduced, which forms a series of lanthanum
complexes with the ligand in both anionic and neutral forms. Stoichiometric control alone …
complexes with the ligand in both anionic and neutral forms. Stoichiometric control alone …
Structural, Spectroscopic, and Computational Analysis of Heterometallic Thorium Phosphinidiide Complexes
ML Tarlton, SP Vilanova, MG Kaumini… - Inorganic …, 2021 - ACS Publications
To synthesize complexes with thorium–phosphorus multiple-bond character, reactions of
(C5Me5) 2Th [P (H) Mes] 2 with monovalent alkali-metal bases, MN (SiMe3) 2, as well as …
(C5Me5) 2Th [P (H) Mes] 2 with monovalent alkali-metal bases, MN (SiMe3) 2, as well as …
(R)‐BINOL‐6,6'‐bistriflone: Shortened Synthesis, Characterization, and Enantioselective Catalytic Applications
O Mouhtady, T Castellan… - European Journal of …, 2021 - Wiley Online Library
The title compound, characterized by X‐ray crystallography, was accessed in 4 steps with
92% ee. and 25% yield from an O‐protected (R)‐BINOL precursor. This revised synthetic …
92% ee. and 25% yield from an O‐protected (R)‐BINOL precursor. This revised synthetic …
Spectroscopic and Theoretical Insights into Surprisingly Effective Sm(III) Extraction from Alkaline Aqueous Media by o-Phenylenediamine-Derived Sulfonamides
EV Govor, AN Morozov, AA Rains, AM Mebel… - Inorganic …, 2020 - ACS Publications
Alkaline high-level waste (HLW) generated as a result of years of nuclear weapons
production has complicated composition and requires comprehensive treatment methods …
production has complicated composition and requires comprehensive treatment methods …
An investigation of the binding of (S)-monothioBINOLate to rare earth metal cations
GB Panetti, EJ Varela, MR Gau… - … , Sulfur, and Silicon …, 2019 - Taylor & Francis
Two novel rare earth compounds have been synthesized using the previously reported (S)-
MonoThioBINOL [(S)-H 2-MTB],(S)-2-hydroxy-2′-mercapto-1, 1′-binaphthyl). We have …
MonoThioBINOL [(S)-H 2-MTB],(S)-2-hydroxy-2′-mercapto-1, 1′-binaphthyl). We have …