Advances in cluster superatoms for a 3D periodic table of elements

Z Luo, S Lin - Coordination Chemistry Reviews, 2024 - Elsevier
Clusters that mimic elemental atoms in the periodic table are known as superatoms which
open up a new window to design functional materials and catalysts by atomic construction …

Emergent Research Trends on the Structural Relaxation Dynamics of Molecular Clusters: From Structure–Property Relationship to New Function Prediction

B Xue, Y Lai, L Cai, Y Liu, JF Yin… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Molecular clusters (MCs) are monodispersed, precisely defined ensembles of
atom collections featured with shape-persistent architectures that can deliver certain …

Cluster-assembled superatomic crystals for chirality-dependent charge-to-spin conversion

Y Zhao, J Zhao, Y Guo, S Zhou - npj Quantum Materials, 2023 - nature.com
In chiral materials, spins and chirality are coupled via spin-orbit interaction, provoking a fast-
growing field of chiral spintronics. Compared with the widely explored chiral molecules …

Modern cluster design based on experiment and theory

T Tsukamoto, T Kambe, T Imaoka… - Nature Reviews …, 2021 - nature.com
For decades, chemists have explored cluster compounds according to theoretical models
that have proved too simplistic to accurately predict cluster properties, stabilities and …

Au20(tBu3P)8: A Highly Symmetric Metalloid Gold Cluster in Oxidation State 0

F Fetzer, N Pollard, NC Michenfelder… - Angewandte Chemie …, 2022 - Wiley Online Library
Metalloid gold clusters have unique properties with respect to size and structure and are key
intermediates in studying transitions between molecular compounds and the bulk phase of …

Atom hybridization of metallic elements: Emergence of subnano metallurgy for the post-nanotechnology

T Imaoka, A Kuzume, M Tanabe, T Tsukamoto… - Coordination Chemistry …, 2023 - Elsevier
Miniaturizing metallic materials from the nanoscale to the atomic scale transforms the
structures and physical properties. Among these sub-nanoscale materials, some catalysts …

The global minimum of Ag 30: a prolate spheroidal structure predicted using a genetic algorithm with incomplete local optimizations at the DFT level

W Liu, L Huang, L Meng, J Hu, X Xing - Physical Chemistry Chemical …, 2023 - pubs.rsc.org
Genetic algorithms have been widely used to explore global minimum points of atomic
clusters, and their incorporation with ab initio calculations (including density functional …

Unveiling Hierarchical Self‐Assembly of Triazolylferrocenyl Dendrimers: Producing Non‐Traditional Intrinsically Green Fluorescent Vesosomes for Nanotheranostics

CB Braga, G Perli, Q Wang, L Wylie… - Advanced …, 2024 - Wiley Online Library
Dendrimers and supramolecular chemistry continue to fascinate researchers due to the
endless unrevealed potential of their combination. This study investigates the self‐assembly …

Atomic Cluster Is a Strong Broadband Midinfrared Chromophore

AE Green, AS Gentleman, W Schöllkopf, A Fielicke… - Physical Review Letters, 2021 - APS
We report an intense broadband midinfrared absorption band in the Au 10+ cluster in a
region in which only molecular vibrations would normally be expected. Observed in the …

Single atom alloy clusters Agn− 1X−(X= Cu, Au; n= 7–20) reacting with O2: Symmetry-adapted orbital model

Q Du, L Huang, J Fu, Y Cao, X Xing… - The Journal of Chemical …, 2023 - pubs.aip.org
Single atom alloy AgCu catalysts have attracted great attention, since doping the single Cu
atom introduces narrow free-atom-like Cu 3d states in the electronic structure. These …