Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

Transition metal-catalyzed cyclization reactions of unsaturated substrates have become one
of the most important and useful methodologies for the preparation of heterocycles. To this …

Conspectus Inter-or intramolecular hydroamination reactions are a paradigmatic example of
modern sustainable organic chemistry, as they are a catalytic, 100% atom-economical, and …

Pyrroles are structurally important heterocycles. However, the synthesis of polysubstituted
pyrroles is often challenging. Here, we report a multicomponent, Ti-catalysed formal [2+ 2+ …

Conspectus Nitrogen-based heterocycles are important frameworks for pharmaceuticals,
natural products, organic dyes for solar cells, and many other applications. Catalysis for the …

Hydroaminoalkylation is a 100% atom economic method for forming Csp3–Csp3 bonds
through C–H activation α to an amine and subsequent reaction with an alkene. When …

Conspectus Titanium, as the second most abundant transition metal in the earth's crust,
lends itself as a sustainable and inexpensive resource in catalysis. Its nontoxicity and …

Here, we reported for the first time a mechanistically distinctive cobalt-catalyzed
Markovnikov-type sequential semihydrogenation/hydrohydrazidation of aliphatic terminal …

This review highlights the recent achievements in replacing precious-metal-based catalysts
with nonprecious-metal-based catalysts in two important syntheses: hydroamination and C …