Relevance of weak hydrogen bonds in the conformation of organic compounds and bioconjugates: evidence from recent experimental data and high-level ab initio …
O Takahashi, Y Kohno, M Nishio - Chemical reviews, 2010 - ACS Publications
Organic chemists tend to consider the conformation of compounds as a consequence of
repulsive steric interactions. In other words,“the steric effect” means “repulsive” in many …
repulsive steric interactions. In other words,“the steric effect” means “repulsive” in many …
CH/π hydrogen bonds in organic reactions
M Nishio - Tetrahedron, 2005 - Elsevier
The CH/p interaction 1,† is the weakest extreme of hydrogen bonds 2, 3 that occurs between
a soft acid (CH) and a soft base (p-system) 4, 5 in the context of Pearson's HSAB principle …
a soft acid (CH) and a soft base (p-system) 4, 5 in the context of Pearson's HSAB principle …
The CH/π hydrogen bond in chemistry. Conformation, supramolecules, optical resolution and interactions involving carbohydrates
M Nishio - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
The CH/π hydrogen bond is an attractive molecular force occurring between a soft acid and
a soft base. Contribution from the dispersion energy is important in typical cases where …
a soft base. Contribution from the dispersion energy is important in typical cases where …
CH/π hydrogen bonds in crystals
M Nishio - CrystEngComm, 2004 - pubs.rsc.org
The nature and characteristics of the CH/π interaction are discussed by comparison with
other weak molecular forces such as the CH/O and OH/π interaction. The CH/π interaction is …
other weak molecular forces such as the CH/O and OH/π interaction. The CH/π interaction is …
CH/π hydrogen bonds in organic and organometallic chemistry
M Nishio, Y Umezawa, K Honda, S Tsuboyama… - …, 2009 - pubs.rsc.org
This treatise is an update to a preceding highlight (CH/π hydrogen bonds in crystals)
published in this journal 5 years ago (M. Nishio, CrystEngComm, 2004, 6, 130–156). After …
published in this journal 5 years ago (M. Nishio, CrystEngComm, 2004, 6, 130–156). After …
Nature and physical origin of CH/π interaction: significant difference from conventional hydrogen bonds
S Tsuzuki, A Fujii - Physical Chemistry Chemical Physics, 2008 - pubs.rsc.org
Recently reported high-level ab initio calculations and gas phase spectroscopic
measurements show that the nature of CH/π interactions is considerably different from …
measurements show that the nature of CH/π interactions is considerably different from …
Hydrogen bonding and π–π interactions in imidazolium-chloride ionic liquid clusters
RP Matthews, T Welton, PA Hunt - Physical Chemistry Chemical …, 2015 - pubs.rsc.org
A systematic electronic structure analysis of hydrogen bonding (H-bonding), anion–π+ and
π+–π+ interactions present in [C1C1im] Cl ion-pairs (IPs) and selected [C1C1im] 2Cl2 IP …
π+–π+ interactions present in [C1C1im] Cl ion-pairs (IPs) and selected [C1C1im] 2Cl2 IP …
Magnitude of the CH/π interaction in the gas phase: Experimental and theoretical determination of the accurate interaction energy in benzene-methane
K Shibasaki, A Fujii, N Mikami… - The Journal of Physical …, 2006 - ACS Publications
The accurate CH/π interaction energy of the benzene− methane model system was
experimentally and theoretically determined. In the experiment, mass analyzed threshold …
experimentally and theoretically determined. In the experiment, mass analyzed threshold …
CH/π interactions
S Tsuzuki - Annual Reports Section" C"(Physical Chemistry), 2012 - pubs.rsc.org
Recent gas phase measurements and high level ab initio calculations of the CH/π
interactions show that the nature of the CH/π interactions is significantly different from …
interactions show that the nature of the CH/π interactions is significantly different from …
Saturated hydrocarbon− benzene complexes: theoretical study of cooperative CH/π interactions
J Ran, MW Wong - The Journal of Physical Chemistry A, 2006 - ACS Publications
High-level ab initio calculations at the CCSD (T)/aug-cc-pVTZ//MP2/aug (d, p)-6-311G (d, p)
level were employed to investigate the cooperative CH/π effects between the π face of …
level were employed to investigate the cooperative CH/π effects between the π face of …