Dynamics of excitons in conjugated molecules and organic semiconductor systems

OP Dimitriev - Chemical Reviews, 2022 - ACS Publications
The exciton, an excited electron–hole pair bound by Coulomb attraction, plays a key role in
photophysics of organic molecules and drives practically important phenomena such as …

Recent Developments on Understanding Charge Transfer in Molecular Electron Donor‐Acceptor Systems

X Chen, X Zhang, X Xiao, Z Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Charge transfer (CT) in molecular electron donor‐acceptor systems is pivotal for artificial
photosynthesis, photocatalysis, photovoltaics and fundamental photochemistry. We …

Achieving high circularly polarized luminescence with push–pull helicenic systems: from rationalized design to top-emission CP-OLED applications

K Dhbaibi, L Abella, S Meunier-Della-Gatta… - Chemical …, 2021 - pubs.rsc.org
While the development of chiral molecules displaying circularly polarized luminescence
(CPL) has received considerable attention, the corresponding CPL intensity, glum, hardly …

Tuning the fluorescence and the intramolecular charge transfer of phenothiazine dipolar and quadrupolar derivatives by oxygen functionalization

Y Rout, C Montanari, E Pasciucco… - Journal of the …, 2021 - ACS Publications
A series of new naphthalimide and phenothiazine-based push–pull systems (NPI-PTZ1–5),
in which we structurally modulate the oxidation state of the sulfur atom in the thiazine ring, ie …

Revisiting the non-fluorescence of nitroaromatics: presumption versus reality

YM Poronik, B Sadowski, K Szychta… - Journal of Materials …, 2022 - pubs.rsc.org
The electronically excited singlet states of nitroaromatic compounds are often presumed to
be essentially non-fluorescent. Nonetheless, a growing number of reports in the literature …

Alkoxy-substituted quadrupolar fluorescent dyes

Y Feng, PJ Das, RM Young, PJ Brown… - Journal of the …, 2022 - ACS Publications
Polar and polarizable π-conjugated organic molecules containing push–pull chromophores
have been investigated extensively in the past. Identifying unique backbones and building …

Excited-state symmetry breaking in quadrupolar pull–push–pull molecules: dicyanovinyl vs. cyanophenyl acceptors

P Verma, M Tasior, P Roy, SR Meech… - Physical Chemistry …, 2023 - pubs.rsc.org
A significant number of quadrupolar dyes behave as their dipolar analogues when
photoexcited in polar environments. This is due to the occurrence of excited-state symmetry …

Data analysis in transient electronic spectroscopy–an experimentalist's view

JS Beckwith, CA Rumble, E Vauthey - International Reviews in …, 2020 - Taylor & Francis
Time-resolved electronic spectroscopy has grown into a technique that provides hundreds to
thousands of electronic spectra with femtosecond time resolution. This enables complex …

Excited-state symmetry breaking is an ultrasensitive tool for probing microscopic electric fields

B Dereka, N Maroli, YM Poronik, DT Gryko… - Chemical …, 2024 - pubs.rsc.org
Microscopic electric fields are increasingly found to play a pivotal role in catalysis of
enzymatic and chemical reactions. Currently, the vibrational Stark effect is the main …

Excited-State Symmetry Breaking and Localization in a Noncentrosymmetric Electron Donor–Acceptor–Donor Molecule

B Dereka, E Balanikas, A Rosspeintner… - The Journal of …, 2024 - ACS Publications
Electronic excitation in quadrupolar conjugated molecules rapidly localizes on a single
electron donor–acceptor (DA) branch when in polar environments. The loss of center of …