[Mo3S13]2− as a Model System for Hydrogen Evolution Catalysis by MoSx: Probing Protonation Sites in the Gas Phase by Infrared Multiple Photon Dissociation …

A Baloglou, M Plattner, M Ončák… - Angewandte Chemie …, 2021 - Wiley Online Library
Materials based on molybdenum sulfide are known as efficient hydrogen evolution reaction
(HER) catalysts. As the binding site for H atoms on molybdenum sulfides for the catalytic …

Decomposition of Halogenated Molybdenum Sulfide Dianions [Mo3S7X6]2– (X = Cl, Br, I)

M Pritzi, TF Pascher, ML Grutza, P Kurz… - Journal of the …, 2022 - ACS Publications
Molybdenum sulfides are considered a promising and inexpensive alternative to platinum as
a catalyst for the hydrogen evolution reaction. In this study, we perform collision-induced …

[HTML][HTML] Insight into ethylene interactions with molybdenum suboxide cluster anions from photoelectron spectra of chemifragments

RN Schaugaard, JE Topolski, M Ray… - The Journal of …, 2018 - pubs.aip.org
Recent studies on reactions between Mo x O y− cluster anions and H 2 O/C 2 H 4 mixtures
revealed a complex web of addition, hydrogen evolution, and chemifragmentation reactions …

Rearrangement and decomposition pathways of bare and hydrogenated molybdenum oxysulfides in the gas phase

M Pritzi, TF Pascher, ML Grutza, P Kurz… - Physical Chemistry …, 2022 - pubs.rsc.org
Molybdenum sulfides and molybdenum oxysulfides are considered a promising and cheap
alternative to platinum as a catalyst for the hydrogen evolution reaction (HER). To better …

Hydrogen evolution from water reactions with molybdenum sulfide cluster anions

JE Topolski, AK Gupta, KA Nickson… - International Journal of …, 2018 - Elsevier
A study of reactions between a distribution of 98 Mo x S y-clusters ranging from sub-sulfide
(x∼ y) to hypersulfide (y> 2x) is presented, compared with previous studies on homologous …

Thermal O–H Bond Activation of Water As Mediated by Heteronuclear [Al2Mg2O5]•+: Evidence for Oxygen-Atom Scrambling

C Geng, J Li, T Weiske, H Schwarz - Journal of the American …, 2018 - ACS Publications
Mechanistic insight into the thermal O–H bond activation of water by the cubane-like,
prototypical heteronuclear oxide cluster [Al2Mg2O5]•+ has been derived from a combined …

Lanthanide oxides: From diatomics to high-spin, strongly correlated homo-and heterometallic clusters

C Huizenga, HP Hratchian… - The Journal of Physical …, 2021 - ACS Publications
Small lanthanide (Ln) oxide clusters present both experimental and theoretical challenges
because of their partially filled, core-like 4f n orbitals, a feature that results in a plethora of …

Using anion photoelectron spectroscopy of cluster models to gain insights into mechanisms of catalyst-mediated H 2 production from water

AJ McMahon, CC Jarrold - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
Metal oxide cluster models of catalyst materials offer a powerful platform for probing the
molecular-scale features and interactions that govern catalysis. This perspective gives an …

Structural Properties of Gas-Phase Molybdenum Oxide Clusters [Mo4O13]2−, [HMo4O13], and [CH3Mo4O13] Studied by Collision-Induced Dissociation

M Plattner, A Baloglou, M Ončák… - Journal of The …, 2019 - ACS Publications
Molybdenum oxide-based catalysts are widely used for the ammoxidation of toluene,
methanation of CO, or hydrodeoxygenation. As a first step towards a gas-phase model …

[Mo3S13] 2− als Modellsystem für die katalytische Wasserstoffentwicklung durch MoSx: Untersuchung der Protonierungsstellen in der Gasphase durch Infrarot …

A Baloglou, M Plattner, M Ončák, ML Grutza… - Angewandte …, 2021 - Wiley Online Library
Materialien auf Molybdänsulfidbasis sind als effiziente Katalysatoren für die
Wasserstoffentwicklung (hydrogen evolution reaction, HER) bekannt. Da die Bindungsstelle …