Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

In the past two decades, metal–organic frameworks (MOFs) or porous coordination polymers
(PCPs) assembled from metal ions or clusters and organic linkers via metal–ligand …

A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Conspectus The fine design and regulation of catalysts play critical roles in the development
of catalysis. The microenvironment, which gives rise to unique spatial structures and …

Conspectus Emissive species are powerful for luminescent detection with high sensitivity
and simple procedure and for light-emitting diode (LED) lighting because of their high …

Metal–organic frameworks (MOFs) have emerged as one of the most widely investigated
materials in catalysis mainly due to their excellent component tunability, high surface area …

Recent advances in organic chemistry and materials chemistry have enabled the porosity of
new materials to be accurately controlled on the nanometer scale. In this context, metal …

Selective organic transformations using metal–organic frameworks (MOFs) and MOF-based
heterogeneous catalysts have been an intriguing but challenging research topic in both the …

When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …

The pores in metal–organic frameworks (MOFs) can be functionalized by placing chemical
entities along the backbone and within the backbone. This chemistry is enabled by the …