Complex polymer architectures using ring-opening metathesis polymerization: synthesis, applications, and practical considerations

SE Blosch, SJ Scannelli, M Alaboalirat… - Macromolecules, 2022 - ACS Publications
Nature shows us that complex molecular architectures lead to unique material properties,
and these observations have driven polymer scientists to synthesize complex architectures …

Controllable synthesis and structural design of novel all-organic polymers toward high energy storage dielectrics

H Gong, Q Ji, Y Cheng, J Xiong, M Zhang… - Frontiers in …, 2022 - frontiersin.org
As the core unit of energy storage equipment, high voltage pulse capacitor plays an
indispensable role in the field of electric power system and electromagnetic energy related …

Monomer Emulsified Aqueous Ring-Opening Metathesis Polymerization (ME-ROMP) for the Synthesis of Water-Soluble Molecular Bottlebrushes with a Precise …

W Hou, Y Zhou, X Yin, Y Chen, Y Shi - Macromolecules, 2023 - ACS Publications
Water-soluble molecular bottlebrushes (MBBs) with various functions and tunable
morphologies have found promising application prospects in the biorelevant field. However …

Bottlebrush Networks: A Primer for Advanced Architectures

BR Clarke, CL Witt, M Ilton, AJ Crosby… - Angewandte …, 2024 - Wiley Online Library
Bottlebrush networks (BBNs) are an exciting new class of materials with interesting physical
properties derived from their unique architecture. While great strides have been made in our …

Influence of the Norbornene Anchor Group in Ru-Mediated Ring-Opening Metathesis Polymerization: Synthesis of Linear Polymers

SJ Scannelli, A Paripati, JR Weaver, C Vu… - …, 2023 - ACS Publications
Ring-opening metathesis polymerization (ROMP) mediated by Grubbs' first-generation
catalyst [G1,(PCy3) 2 (Cl) 2RuCHPh] and Grubbs' third-generation catalyst [G3,(H2IMes)(Cl) …

Grafting-To and From for Multiplexed Chemical-Warfare-Agent Responsive Polymer Brushes

Q He, SXL Luo, T Jin, M Liu, S Park… - Chemistry of …, 2023 - ACS Publications
Surface-tethered polymers have important applications in functional polymer coatings,
particularly for the development of chemically responsive surfaces. Here, we combined the …

Ring-opening metathesis polymerization of norbornene–benzoladderene (macro) monomers

SJ Scannelli, M Alaboalirat, D Troya, JB Matson - Polymer Chemistry, 2023 - pubs.rsc.org
Norbornene-based monomers are common starting points in ring-opening metathesis
polymerization (ROMP) due to their high ring strain, and recent reports highlight how the …

Tough, self-healing, recyclable bottlebrush polyurethane elastomer with a skin-like strain-adaptive-strengthening property

S Shan, X Wu, Y Lin, A Zhang - ACS Applied Polymer Materials, 2022 - ACS Publications
Bottlebrush polymers consisting of linear polymer backbone and polymeric side-chains are
of significant interest for an extensive variety of potential applications that include drug …

Radical–radical coupling effects in the direct-growth grafting-through synthesis of bottlebrush polymers using RAFT and ROMP

M Alaboalirat, C Vu, JB Matson - Polymer Chemistry, 2022 - pubs.rsc.org
The direct-growth technique was used to synthesize several macromonomers (MMs)
employing reversible addition–fragmentation chain transfer (RAFT) polymerization by …

Ultrafast Monomer Emulsified Aqueous Ring-Opening Metathesis Polymerization for the Synthesis of Water-Soluble Polynorbornenes with Precise Structure

W Hou, X Yin, Y Chen, J Du, Y Chen, Y Shi - ACS Macro Letters, 2023 - ACS Publications
Ring-opening metathesis polymerization (ROMP) in an aqueous medium provides an
important environmentally friendly platform for the preparation of water-soluble polymeric …