Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Over the past two decades, the C–H bond activation and functionalization reaction has been
known as a prevailing method for the construction of carbon–carbon and carbon …

The functionalization of C–H bonds in organic molecules containing functional groups has
been one of the holy grails of catalysis. One synthetically important approach to the diverse …

Abstract The regio‐, site‐, stereo‐or chemoselective homogeneous catalytic transformations
are extremely important for the growth/success of the current chemical industry. Based on …

A method of para‐selective borylation of aromatic amides is described. The borylation
proceeded via an unprecedented substrate–ligand distortion between the twisted aromatic …

Aryl sulfones and aryl sulfonamides are of great importance in organic synthesis and
medicinal chemistry. Although ortho‐C− H functionalization of aryl sulfonyl compounds has …

This work reports a site‐selective C− H borylation of pyridines at the ortho‐position with
pinacolborane enabled by an yttrocene catalyst. The reaction provides a new family of 2 …

1, 1′-Bi-2-naphthol (BINOL) has been extensively used as the chirality source in the fields
of molecular recognition, asymmetric synthesis, and materials science. The direct …

An efficient and straightforward approach for the synthesis of C7 site-selective BINOL
derivatives has been achieved via cost-effective Co (III)-catalyzed C–H cascade …

Organoboron compounds continue contributing substantially to advances in organic
chemistry with their increasing role as both synthetic intermediates and target compounds …