The surface science approach toward understanding automotive exhaust conversion catalysis at the atomic level

BE Nieuwenhuys - Advances in catalysis, 1999 - Elsevier
This review focuses on the reactions and catalysts used for control of emissions of exhaust
gases for gasoline-fueled automobiles with emphasis on fundamental understanding of the …

NO chemisorption and reactions on metal surfaces: a new perspective

WA Brown, DA King - The Journal of Physical Chemistry B, 2000 - ACS Publications
NO adsorption on metal surfaces has been studied extensively due to its important role in
many catalytic processes. In the past, it was recognized that the tendency for a metal surface …

Nitric Oxide Decomposition on Small Rhodium Clusters, Rhn+/-

ML Anderson, MS Ford, PJ Derrick… - The Journal of …, 2006 - ACS Publications
The decomposition of nitric oxide on small charged rhodium clusters Rh n+/-(6< n< 30) has
been investigated by Fourier transform ion cyclotron resonance mass spectrometry. For both …

Nitrogen molecule adsorption on cationic tantalum clusters and rhodium clusters and desorption from their nitride clusters studied by thermal desorption spectrometry

F Mafuné, Y Tawaraya, S Kudoh - The Journal of Physical …, 2016 - ACS Publications
Adsorption and desorption of N2 molecules onto cationic Ta and Rh clusters in the gas
phase were investigated in the temperature range of 300–1000 K by using thermal …

Ab initio density-functional study of NO adsorption on close-packed transition and noble metal surfaces: II. Dissociative adsorption

M Gajdoš, J Hafner, A Eichler - Journal of Physics: Condensed …, 2005 - iopscience.iop.org
Following our investigation of molecular NO adsorption (Gajdos et al 2006 J. Phys.:
Condens. Matter 18 13), the dissociation of NO molecules on the close-packed surfaces of …

Kinetic description of site ensembles on catalytic surfaces

NK Razdan, A Bhan - … of the National Academy of Sciences, 2021 - National Acad Sciences
We demonstrate that the Langmuir–Hinshelwood formalism is an incomplete kinetic
description and, in particular, that the Hinshelwood assumption (ie, that adsorbates are …

Thermal desorption and reaction of NO adsorbed on rhodium cluster ions studied by thermal desorption spectroscopy

Y Tawaraya, S Kudoh, K Miyajima… - The Journal of Physical …, 2015 - ACS Publications
Cationic rhodium clusters, Rh n+(n= 4–8), were prepared in the gas phase by the laser
ablation of a Rh rod. The Rh n+ clusters were introduced into a reaction gas cell filled with …

Role of adsorbed nitrogen in the catalytic reduction of NO on rhodium surfaces

F Zaera, CS Gopinath - The Journal of chemical physics, 1999 - pubs.aip.org
The role of surface nitrogen in the kinetics of the NOCO conversion reaction on Rh (111)
under steady-state catalytic conditions was explored by using collimated molecular beams …

Adsorption Forms of NO on Rhn+ (n = 6–16) Revealed by Infrared Multiple Photon Dissociation Spectroscopy

T Nagata, K Koyama, S Kudoh, K Miyajima… - The Journal of …, 2017 - ACS Publications
The adsorption of NO on cationic Rh clusters, Rh n+(n= 6–16), was studied by IRMPD
spectroscopy using FELIX in combination with DFT calculations. The IRMPD spectra show …

Decomposition of nitric oxide by rhodium cluster cations at high temperatures

T Nagata, K Kawada, X Chen, M Yamaguchi… - Physical Chemistry …, 2021 - pubs.rsc.org
Decomposition reactions of NO molecules on gas-phase Rhn+ (n= 6–9) clusters were
investigated by gas-phase thermal desorption spectrometry and density functional theory …