Decoupling ion transport and matrix dynamics to make high performance solid polymer electrolytes
Transport of ions through solid polymeric electrolytes (SPEs) involves a complicated
interplay of ion solvation, ion–ion interactions, ion-polymer interactions, and free volume …
interplay of ion solvation, ion–ion interactions, ion-polymer interactions, and free volume …
Ion correlations and their impact on transport in polymer-based electrolytes
The development of next-generation polymer-based electrolytes for energy storage
applications would greatly benefit from a deeper understanding of transport phenomena in …
applications would greatly benefit from a deeper understanding of transport phenomena in …
Molecular dynamics simulations of ion-containing polymers using generic coarse-grained models
Molecular dynamics simulations with generic bead–spring models have been instrumental
in revealing the molecular-scale behavior that underlies structure–property relationships of …
in revealing the molecular-scale behavior that underlies structure–property relationships of …
The role of backbone polarity on aggregation and conduction of ions in polymer electrolytes
The usual understanding in polymer electrolyte design is that an increase in the polymer
dielectric constant results in reduced ion aggregation and therefore increased ionic …
dielectric constant results in reduced ion aggregation and therefore increased ionic …
Design of polymer blend electrolytes through a machine learning approach
We apply a machine learning (ML) technique to the multiobjective design of polymer blend
electrolytes. In particular, we are interested in maximizing electrolyte performance measured …
electrolytes. In particular, we are interested in maximizing electrolyte performance measured …
Polymer Architecture-Induced Trade-off between Conductivities and Transference Numbers in Salt-Doped Polymeric Ionic Liquids
Recent experiments have demonstrated that polymeric ionic liquids that share the same
cation and anion but possess different architectures can exhibit markedly different …
cation and anion but possess different architectures can exhibit markedly different …
The Importance of Morphology on Ion Transport in Single-Ion, Comb-Branched Copolymer Electrolytes: Experiments and Simulations
S Kadulkar, ZW Brotherton, AL Lynch… - …, 2023 - ACS Publications
Single-ion conducting polymer electrolytes (SICPEs) offer high lithium transference numbers
and desirable physical properties while maintaining moderate conductivities. Bottlebrush …
and desirable physical properties while maintaining moderate conductivities. Bottlebrush …
Li+ Transport in Single-Ion Conducting Side-Chain Polymer Electrolytes with Nanoscale Self-Assembly of Ordered Ionic Domains
Li-ion batteries based on organic liquid electrolytes have been commercialized for decades.
However, the flammability of the liquid electrolyte and propensity for reaction with metallic …
However, the flammability of the liquid electrolyte and propensity for reaction with metallic …
Investigation of the electrochemical performance of Mg-ion batteries based on PVDF-HFP thin polymer electrolyte films
MJ Hussain, CS Espenti, YVM Reddy… - Materials Chemistry and …, 2024 - Elsevier
In the present work, poly (vinylidene fluoride-hexafluoropropylene): magnesium
trifluoromethanesulfonate (PVDF-HFP: MgTf) polymer electrolytic films with a porous …
trifluoromethanesulfonate (PVDF-HFP: MgTf) polymer electrolytic films with a porous …
Quantifying single-ion transport in percolated ionic aggregates of polymer melts
Single-ion conducting polymers such as ionomers are promising battery electrolyte
materials, but it is critical to understand how rates and mechanisms of free cation transport …
materials, but it is critical to understand how rates and mechanisms of free cation transport …