This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews …

Vinyl epoxides are molecules with a rich chemistry because of the strained oxirane, already
a reactive moiety on its own, in proximity with a carbon− carbon double bond. The chemistry …

The main objective of this review is to provide a comprehensive survey of methods used for
stereoselective construction of carbon–nitrogen bonds during the total synthesis of nitrogen …

The asymmetric synthesis of allylic amines is an important research area in modern
synthetic organic chemistry, primarily due to the inherent utility and ubiquity of this functional …

Described herein is an organocatalytic enantioselective desymmetrizing cycloisomerization
of arylsulfonyl‐protected ynamide cyclohexanones, representing the first metal‐free …

Two unprecedented C, C-linked dimeric indolizidine alkaloids, flueggines A (1) and B (2),
were isolated from the twigs and leaves of Flueggea virosa. The structures and absolute …

A direct catalytic asymmetric vinylogous Mannich-type reaction has been disclosed in good
yield, excellent regio-, diastereo-and enantioselectivity. The key to control the …

The identification of new chemical entities is of paramount importance to the biomedical
sciences for the development of novel therapeutic agents, and natural products have …

When the principle of vinylogy is applied to imines as electrophiles, the so-called vinylogous
Mannich reaction (VMR), γ-aminocarbonyl (such as butenolides) and β-aminocarbonyl …