Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures

XZ Li, CB Tian, QF Sun - Chemical Reviews, 2022 - ACS Publications
Lanthanide supramolecular chemistry is a fast growing and intriguing research field due to
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …

[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

PHI: A powerful new program for the analysis of anisotropic monomeric and exchange‐coupled polynuclear d‐ and f‐block complexes

NF Chilton, RP Anderson, LD Turner… - Journal of …, 2013 - Wiley Online Library
A new program, PHI, with the ability to calculate the magnetic properties of large spin
systems and complex orbitally degenerate systems, such as clusters of d‐block and f‐block …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies

JH Jia, QW Li, YC Chen, JL Liu, ML Tong - Coordination Chemistry …, 2019 - Elsevier
Incorporation of two characters into one molecular entity is an effective way to afford
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Recent advances in luminescent lanthanide based Single-Molecule Magnets

J Long, Y Guari, RAS Ferreira, LD Carlos… - Coordination Chemistry …, 2018 - Elsevier
Abstract Luminescent lanthanide-based Single-Molecule Magnets (SMM) are multifunctional
molecule-based materials that combine luminescence and magnetic properties in the same …

Magnetic relaxation pathways in lanthanide single-molecule magnets

RJ Blagg, L Ungur, F Tuna, J Speak, P Comar… - Nature …, 2013 - nature.com
Single-molecule magnets are compounds that exhibit magnetic bistability caused by an
energy barrier for the reversal of magnetization (relaxation). Lanthanide compounds are …