Structure–reactivity–property relationships in covalent adaptable networks
V Zhang, B Kang, JV Accardo… - Journal of the American …, 2022 - ACS Publications
Polymer networks built out of dynamic covalent bonds offer the potential to translate the
control and tunability of chemical reactions to macroscopic physical properties. Under …
control and tunability of chemical reactions to macroscopic physical properties. Under …
Traffic lights for catalysis: Stimuli‐responsive molecular and extended catalytic systems
GC Thaggard, J Haimerl, RA Fischer… - Angewandte Chemie …, 2023 - Wiley Online Library
The advances made in the field of stimuli‐responsive catalysis during the last five years with
a focus on the novel recently‐emerged directions and applications have been surveyed …
a focus on the novel recently‐emerged directions and applications have been surveyed …
Controlling Dynamics of Associative Networks through Primary Chain Length
Dynamic networks couple the robust nature of thermosets with the shapeability and
recyclability of thermoplastics. Though a wealth of exchange chemistries can be leveraged …
recyclability of thermoplastics. Though a wealth of exchange chemistries can be leveraged …
Hyperbranched dynamic crosslinking networks enable degradable, reconfigurable, and multifunctional epoxy vitrimer
Y Zhang, H Yan, R Yu, J Yuan, K Yang, R Liu… - Advanced …, 2024 - Wiley Online Library
Degradation and reprocessing of thermoset polymers have long been intractable challenges
to meet a sustainable future. Star strategies via dynamic cross‐linking hydrogen bonds …
to meet a sustainable future. Star strategies via dynamic cross‐linking hydrogen bonds …
Photoswitchable dynamic conjugate addition-elimination reactions as a tool for light-mediated click and clip chemistry
H Lu, H Ye, M Zhang, Z Liu, H Zou, L You - Nature Communications, 2023 - nature.com
Phototriggered click and clip reactions can endow chemical processes with high
spatiotemporal resolution and sustainability, but are challenging with a limited scope. Herein …
spatiotemporal resolution and sustainability, but are challenging with a limited scope. Herein …
Dual reactivity based dynamic covalent chemistry: mechanisms and applications
L You - Chemical Communications, 2023 - pubs.rsc.org
Dynamic covalent chemistry (DCC) focuses on the reversible formation, breakage, and
exchange of covalent bonds and assemblies, setting a bridge between irreversible organic …
exchange of covalent bonds and assemblies, setting a bridge between irreversible organic …
Light‐fueled transformations of a dynamic cage‐based molecular system
In a chemical equilibrium, the formation of high‐energy species—in a closed system—is
inefficient due to microscopic reversibility. Here, we demonstrate how this restriction can be …
inefficient due to microscopic reversibility. Here, we demonstrate how this restriction can be …
The Power of Action Plots: Unveiling Reaction Selectivity of Light‐Stabilized Dynamic Covalent Chemistry
Exploiting the optimum wavelength of reactivity for efficient photochemical reactions has
been well‐established based on the development of photochemical action plots. We herein …
been well‐established based on the development of photochemical action plots. We herein …
Internal and external catalysis in boronic ester networks
B Kang, JA Kalow - ACS macro letters, 2022 - ACS Publications
In dynamic materials, the reversible condensation between boronic acids and diols provides
adaptability, self-healing ability, and responsiveness to small molecules and pH. The …
adaptability, self-healing ability, and responsiveness to small molecules and pH. The …
Revisiting Peri‐Aryloxyquinones: From a Forgotten Photochromic System to a Promising Tool for Emerging Applications
AG Lvov, LS Klimenko, VN Bykov… - Chemistry–A European …, 2024 - Wiley Online Library
Emerging applications of photochromic compounds demand new molecular designs that
can be inspired by some long‐known yet currently forgotten classes of photoswitches. In the …
can be inspired by some long‐known yet currently forgotten classes of photoswitches. In the …