Diboron (4) compounds: from structural curiosity to synthetic workhorse
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …
(4) compounds been extensively explored. Many interesting structural features and reaction …
Transition-metal-free B–B and B–interelement reactions with organic molecules
This review is a guided tour along the activation modes and reactivity of B–B, B–Si, B–N, B–
S, B–Se and B–P reagents, in the absence of any transition metal complex. Here are …
S, B–Se and B–P reagents, in the absence of any transition metal complex. Here are …
Diastereoselective guest-shape dependent [2+ 2]-photodimerization of 2-cyclopenten-1-one trapped within a metal–organic framework
PA Demakov, DN Dybtsev, VP Fedin - Chemical Communications, 2023 - pubs.rsc.org
UV-induced [2+ 2] dimerization of 2-cyclopenten-1-one and 2-methyl-2-cyclopenten-1-one
was successfully carried out in a single-crystal-to-single-crystal manner within a porous …
was successfully carried out in a single-crystal-to-single-crystal manner within a porous …
Crystallography of encapsulated molecules
K Rissanen - Chemical Society Reviews, 2017 - pubs.rsc.org
The crystallography of supramolecular host–guest complexes is reviewed and discussed as
a part of small molecule crystallography. In these complexes, the host binds the guests …
a part of small molecule crystallography. In these complexes, the host binds the guests …
Metal-organic materials with triazine-based ligands: From structures to properties and applications
Triazine-based ligands, featuring C 3-symmetry configuration, electron-deficient and other
triazine moiety determined characteristics, have facilitated the construction of a diverse set of …
triazine moiety determined characteristics, have facilitated the construction of a diverse set of …
B–B bond activation and NHC ring-expansion reactions of diboron (4) compounds, and accurate molecular structures of B 2 (NMe 2) 4, B 2 eg 2, B 2 neop 2 and B 2 …
M Eck, S Würtemberger-Pietsch, A Eichhorn… - Dalton …, 2017 - pubs.rsc.org
In this detailed study we report on the structures of the widely employed diboron (4)
compounds bis (pinacolato) diboron (B2pin2) and bis (neopentyl glycolato) diboron …
compounds bis (pinacolato) diboron (B2pin2) and bis (neopentyl glycolato) diboron …
Hydrogen bonded frameworks: smart materials used smartly
Hydrogen-bonded frameworks (HBFs) have been studied for decades owing to their
fascinating and diverse architectures, always with an eye toward the role of hydrogen …
fascinating and diverse architectures, always with an eye toward the role of hydrogen …
Alkoxide activation of tetra-alkoxy diboron reagents in C–B bond formation: a decade of unpredictable reactivity
JJ Carbó, E Fernández - Chemical Communications, 2021 - pubs.rsc.org
Any attempt to facilitate a new generation of C–B bonds represents a useful tool in organic
synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties …
synthesis. In addition, if that approach highlights the nucleophilic character of boryl moieties …
Crystalline‐sponge‐based structural analysis of crude natural product extracts
Abstract Characterization of complex natural product mixtures to the absolute structural level
of their components often requires significant amounts of starting materials and lengthy …
of their components often requires significant amounts of starting materials and lengthy …
X-ray structure analysis of ozonides by the crystalline sponge method
S Yoshioka, Y Inokuma, V Duplan… - Journal of the …, 2016 - ACS Publications
The crystalline sponge method was used for the X-ray structure analysis of ozonide
compounds. As this new technique requires only microgram quantities of the samples …
compounds. As this new technique requires only microgram quantities of the samples …