We disclose a strategy for Ni-catalyzed dicarbofunctionalization of olefins in styrenes by
intercepting Heck C (sp3)–NiX intermediates with arylzinc reagents. This approach utilizes a …

Abstract β‐Keto amides are a versatile class of compounds that find wide applications in
organic chemistry owing to the juxtaposition of multiple reaction sites within their molecular …

Four amidate-functionalized N-heterocyclic carbene (NHC) rare-earth metal amido
complexes [(κ2-N, O-κ1-L) 2REN (SiMe3) 2](L= 1-(C6H5C═ ONCH2CH2)-3-(CH3) 3C6H2 …

The first examples of the hydroboration of imines with HBpin catalyzed by the commercially
available n-BuLi are reported herein. Good functional group tolerance under mild conditions …

A palladium-catalysed aminocarbonylation of (hetero) aryl iodides has, for the first time,
been accomplished in deep eutectic solvents as environmentally benign and recyclable …

Imine functionality is found in many compounds with important biological activity. Thus, the
development of novel synthetic approaches for imines is important. In this work, it is propose …

Steric bulk around catalytic centers is one of the most important factors determining catalytic
reactivities and selectivities. This paper reports the synthesis of structurally diverse 5-iodo-3 …

A general, safe and scalable reductive protocol, based on the in situ generation of H2 from
aluminum and water, has been developed in deep eutectic solvents for the reduction of …

The first examples of regioselective aryl ortho-C–H functionalization with
diphenyldiazomethane for the construction of Caryl–Nhydrazinato bonds were …

Main observation and conclusion A novel indolyl‐based NCN pincer ligand precursor HL
(HL=(1‐(2‐(CH2) 4NCH2CH2)‐3‐(2, 6‐i Pr2C6H3N= CH) C8H5N)) was rationally and …