Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …
achieving a fundamental understanding on the nature of the active sites in bimetallic …
Recent progress on single-atom catalysts for CO2 electroreduction
Electrocatalytic CO 2 reduction (ECR) can convert CO 2 into various value-added fuels or
chemicals, thus becoming a promising route for balancing the carbon cycle and realizing the …
chemicals, thus becoming a promising route for balancing the carbon cycle and realizing the …
A Heteroleptic Gold Hydride Nanocluster for Efficient and Selective Electrocatalytic Reduction of CO2 to CO
It has been a long-standing challenge to create and identify the active sites of
heterogeneous catalysts, because it is difficult to precisely control the interfacial chemistry at …
heterogeneous catalysts, because it is difficult to precisely control the interfacial chemistry at …
Mediating CO2 Electroreduction Activity and Selectivity over Atomically Precise Copper Clusters
LJ Liu, ZY Wang, ZY Wang, R Wang… - Angewandte …, 2022 - Wiley Online Library
Atomically precise copper clusters are highly desirable catalysts for electrocatalytic CO2
reduction reaction (CO2RR) and provide an ideal platform for elaborating structure–activity …
reduction reaction (CO2RR) and provide an ideal platform for elaborating structure–activity …
Structure Sensitivity in Single-Atom Catalysis toward CO2 Electroreduction
Owing to unique electronic structure and high atom utilization, single-atom catalysts (SACs)
have displayed unprecedented activity and selectivity toward a wide range of catalytic …
have displayed unprecedented activity and selectivity toward a wide range of catalytic …
From Single Crystal to Single Atom Catalysts: Structural Factors Influencing the Performance of Metal Catalysts for CO2 Electroreduction
With the electrochemical CO2 reduction reaction (CO2RR), CO2 can be used as a feedstock
to produce value-added chemicals and fuels while storing renewable energy. For its …
to produce value-added chemicals and fuels while storing renewable energy. For its …
Cu Vacancy Induced Product Switching from Formate to CO for CO2 Reduction on Copper Sulfide
Cu is commonly modified with sulfur to obtain high selectivity for formate since S can
promote the formation of the key* OCHO intermediate along the formate pathway. In the …
promote the formation of the key* OCHO intermediate along the formate pathway. In the …
Atomically Precise Gold Nanoclusters as Model Catalysts for Identifying Active Sites for Electroreduction of CO2
Accurate identification of active sites is critical for elucidating catalytic reaction mechanisms
and developing highly efficient and selective electrocatalysts. Herein, we report the atomic …
and developing highly efficient and selective electrocatalysts. Herein, we report the atomic …
Catalytic Conversion of CO2 over Atomically Precise Gold-Based Cluster Catalysts
X Cai, G Li, W Hu, Y Zhu - ACS Catalysis, 2022 - ACS Publications
There are obstacles with using conventional nanoparticle catalysts for developing atomic-by-
atom tailoring of active sites in the heterogeneous catalysis field. However, atomically …
atom tailoring of active sites in the heterogeneous catalysis field. However, atomically …
Copper Doping Boosts Electrocatalytic CO2 Reduction of Atomically Precise Gold Nanoclusters
Unraveling the atomistic synergistic effects of nanoalloys on the electrocatalytic CO2
reduction reaction (eCO2RR), especially in the presence of copper, is of paramount …
reduction reaction (eCO2RR), especially in the presence of copper, is of paramount …