New horizons for catalysis disclosed by supramolecular chemistry

G Olivo, G Capocasa, D Del Giudice… - Chemical Society …, 2021 - pubs.rsc.org
The adoption of a supramolecular approach in catalysis promises to address a number of
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …

[HTML][HTML] Artificial molecular machines

S Erbas-Cakmak, DA Leigh, CT McTernan… - Chemical …, 2015 - ACS Publications
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …

Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond

AW Heard, JM Suárez, SM Goldup - Nature Reviews Chemistry, 2022 - nature.com
Mechanically interlocked molecules, such as rotaxanes and catenanes, are receiving
increased attention as scaffolds for the development of new catalysts, driven by both their …

Artificial switchable catalysts

V Blanco, DA Leigh, V Marcos - Chemical Society Reviews, 2015 - pubs.rsc.org
Catalysis is key to the effective and efficient transformation of readily available building
blocks into high value functional molecules and materials. For many years research in this …

Chirality in rotaxanes and catenanes

EMG Jamieson, F Modicom, SM Goldup - Chemical Society Reviews, 2018 - pubs.rsc.org
Although chiral mechanically interlocked molecules (MIMs) have been synthesised and
studied, enantiopure examples are relatively under-represented in the pantheon of reported …

Simplicity in the design, operation, and applications of mechanically interlocked molecular machines

AW Heard, SM Goldup - ACS Central Science, 2020 - ACS Publications
Mechanically interlocked molecules are perhaps best known as components of molecular
machines, a view further reinforced by the Nobel Prize in 2016 to Stoddart and Sauvage …

The versatility of squaramides: From supramolecular chemistry to chemical biology

LA Marchetti, LK Kumawat, N Mao, JC Stephens… - Chem, 2019 - cell.com
This review covers recent advances in the use of the squaramide moiety in chemical
research. We focus on the varied applications of squaramides under the broad headings of …

Dissipative catalysis with a molecular machine

C Biagini, SDP Fielden, DA Leigh… - Angewandte …, 2019 - Wiley Online Library
We report on catalysis by a fuel‐induced transient state of a synthetic molecular machine. A
[2] rotaxane molecular shuttle containing secondary ammonium/amine and thiourea stations …

Covalent post-assembly modification in metallosupramolecular chemistry

DA Roberts, BS Pilgrim, JR Nitschke - Chemical Society Reviews, 2018 - pubs.rsc.org
A growing variety of covalent reactions have been employed to achieve the post-assembly
modification (PAM) of self-assembled metallosupramolecular complexes. Covalent PAM …

Distinctive features and challenges in catenane chemistry

HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …