New horizons for catalysis disclosed by supramolecular chemistry
G Olivo, G Capocasa, D Del Giudice… - Chemical Society …, 2021 - pubs.rsc.org
The adoption of a supramolecular approach in catalysis promises to address a number of
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …
[HTML][HTML] Artificial molecular machines
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …
rewards could come from bridging the gap between synthetic molecular systems and the …
Controlling catalyst activity, chemoselectivity and stereoselectivity with the mechanical bond
Mechanically interlocked molecules, such as rotaxanes and catenanes, are receiving
increased attention as scaffolds for the development of new catalysts, driven by both their …
increased attention as scaffolds for the development of new catalysts, driven by both their …
Artificial switchable catalysts
Catalysis is key to the effective and efficient transformation of readily available building
blocks into high value functional molecules and materials. For many years research in this …
blocks into high value functional molecules and materials. For many years research in this …
Chirality in rotaxanes and catenanes
EMG Jamieson, F Modicom, SM Goldup - Chemical Society Reviews, 2018 - pubs.rsc.org
Although chiral mechanically interlocked molecules (MIMs) have been synthesised and
studied, enantiopure examples are relatively under-represented in the pantheon of reported …
studied, enantiopure examples are relatively under-represented in the pantheon of reported …
Simplicity in the design, operation, and applications of mechanically interlocked molecular machines
Mechanically interlocked molecules are perhaps best known as components of molecular
machines, a view further reinforced by the Nobel Prize in 2016 to Stoddart and Sauvage …
machines, a view further reinforced by the Nobel Prize in 2016 to Stoddart and Sauvage …
The versatility of squaramides: From supramolecular chemistry to chemical biology
LA Marchetti, LK Kumawat, N Mao, JC Stephens… - Chem, 2019 - cell.com
This review covers recent advances in the use of the squaramide moiety in chemical
research. We focus on the varied applications of squaramides under the broad headings of …
research. We focus on the varied applications of squaramides under the broad headings of …
Dissipative catalysis with a molecular machine
C Biagini, SDP Fielden, DA Leigh… - Angewandte …, 2019 - Wiley Online Library
We report on catalysis by a fuel‐induced transient state of a synthetic molecular machine. A
[2] rotaxane molecular shuttle containing secondary ammonium/amine and thiourea stations …
[2] rotaxane molecular shuttle containing secondary ammonium/amine and thiourea stations …
Covalent post-assembly modification in metallosupramolecular chemistry
A growing variety of covalent reactions have been employed to achieve the post-assembly
modification (PAM) of self-assembled metallosupramolecular complexes. Covalent PAM …
modification (PAM) of self-assembled metallosupramolecular complexes. Covalent PAM …
Distinctive features and challenges in catenane chemistry
HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …