Gold-catalyzed synthesis of small rings

M Mato, A Franchino, C Garcı́a-Morales… - Chemical …, 2020 - ACS Publications
Three-and four-membered rings, widespread motifs in nature and medicinal chemistry, have
fascinated chemists ever since their discovery. However, due to energetic considerations …

Chemistry and bioactivity of lindenane sesquiterpenoids and their oligomers

J Luo, D Zhang, P Tang, N Wang, S Zhao… - Natural Product …, 2024 - pubs.rsc.org
Covering: 1925 to July 2023 Among the sesquiterpenoids with rich structural diversity and
potential bioactivities, lindenane sesquiterpenoids (LSs) possess a characteristic cis, trans …

Asymmetric total synthesis of natural lindenane sesquiterpenoid oligomers via a triene as a potential biosynthetic intermediate

Z Huang, G Huang, X Wang, S Qin, S Fu… - Angewandte …, 2022 - Wiley Online Library
A previously proposed triene of the lindenane skeleton was synthesized, characterized, and
identified as the common intermediate for the non‐enzymatic synthesis of natural lindenane …

Indium (iii)-catalyzed stereoselective synthesis of tricyclic frameworks by cascade cycloisomerization reactions of aryl 1, 5-enynes

RE Millán, J Rodríguez, LA Sarandeses… - The Journal of …, 2021 - ACS Publications
The indium (III)-catalyzed cascade cycloisomerization reaction of 1, 5-enynes with pendant
aryl nucleophiles is reported. The reaction proceeds in cascade under mild reaction …

Terpenoids of plants from Chloranthaceae family: chemistry, bioactivity, and synthesis

B Zhou, JM Yue - Natural Product Reports, 2024 - pubs.rsc.org
Covering: 1976 to December 2023Chloranthaceae is comprised of four extant genera
(Chloranthus, Sarcandra, Hedyosmum, and Ascarina), totaling about 80 species, many of …

Mechanistic insights into nickel-and gold-catalyzed diastereoselective [4+ 2+ 1] cycloadditions between dienynes and diazo compounds: a DFT study

K Lv, X Bao - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Density functional theory (DFT) calculations were performed to gain an in-depth mechanistic
understanding of Ni (0)-and Au (I)-catalyzed diastereoselective [4+ 2+ 1] cycloadditions …

Asymmetric total syntheses of sarbracholide and shizukaol B

G Huang, Z Huang, X Ma, Z Feng, F Yuan… - Organic Chemistry …, 2023 - pubs.rsc.org
Asymmetric syntheses of lindenane sesquiterpenoid [4+ 2] head-to-back dimers, namely
sarbracholide and shizukaol B, are presented herein. In this synthesis, an MTBD-mediated …

Deciphering Substitution Effects on Reductive Hydroalkoxylation of Alkynyl Aminols for Stereoselective Synthesis of Morpholines and 1, 4-Oxazepanes: Total …

SJ Gharpure, D Kalita, S Somani, J Pal - Organic & Biomolecular …, 2024 - pubs.rsc.org
Acid catalysed reductive etherification of N-propargyl amino alcohols for the stereoselective
synthesis of cis-2, 5/2, 6-disubstituted morpholines and cis-2, 6/2, 7-disubstituted …

Alternative Construction of the Core of Lindenane Sesquiterpenoid.

C Ling, Z Huang, Y Zhou, S Fu… - Chinese Journal of …, 2023 - search.ebscohost.com
Abstract Comprehensive Summary: Alternative synthetic routes toward the tricyclic core of
lindenane sesquiterpenoid are presented herein. The route A features an asymmetric …

Molecular rearrangements

JM Coxon - Organic Reaction Mechanisms· 2013: An annual …, 2016 - Wiley Online Library
This chapter reviews pericyclic reactions in general and reactions where a cascade of
concerted processes with transition states representing superpositions of two pericyclic …