Part of the renaissance in main group chemistry has been a result of the focus on reactivity.
This has led to the development of applications in stoichiometric reactivity and catalysis. In …

In contrast to transition metal-catalysed C–H functionalisation, highly efficient construction of
C–C and C–X (X= N, O, S, B, Si, etc.) bonds through metal-free catalytic C–H …

A nickel‐catalyzed asymmetric reductive hydroarylation of vinyl amides to produce
enantioenriched α‐arylbenzamides is reported. The use of a chiral bisimidazoline (BIm) …

This Perspective describes the development of the field of catalysis and the advent of metal-
free catalysis by focusing on the use of main-group species as frustrated Lewis pair …

Aniline derivatives are frequently encountered in molecules of industrial relevance such as
dyes or antioxidants, which make the development of synthetic methods for the …

Providing new methods for the selective functionalization of small molecules is highly
desirable, because installing molecular diversity in a desired position, for example, allows …

Frustrated Lewis pairs (FLPs), discovered in the last few decades for homogeneous
catalysts and in the last few years also for heterogeneous catalysts, are stimulating the …

Establishing tandem catalytic synthetic strategies based on the use of readily available,
stable, and renewable feedstocks is of great significant for the sustainable advancement of …

In the presence of a thiyl radical species, the catalytic Markovnikov thiol–ene reaction is
challenging because it prefers to proceed via a radical pathway, thereby leading to anti …

Excitation of photoactive electron donor− acceptor (EDA) complexes to generate radical is a
promising approach in radical chemistry. In this study, we introduce a new model of H …