The five-membered, nitrogen-containing pyrroline ring is a privileged structure. This ring is
present in many bioactive compounds from natural sources. Pyrrolines—the dihydro …

The first example of Rh (III)-catalyzed cyclization of arylnitrones to indolines under external
oxidant-free conditions is presented. An intermolecular coupling of arylnitrones with internal …

A Cu-catalyzed protocol has been developed for the rapid construction of a wide spectrum of
structurally interesting spiropyrroline skeletons. This method utilizes readily accessible …

Constructing chiral bispirooxindoles is difficult to achieve but highly attractive owing to their
many potential applications in medicinal chemistry. Here we present an asymmetric [3+ 2] …

An enantioselective ring-opening formal [3+ 2]-cycloaddition of spirovinylcyclopropyl
oxindoles with enals via synergistic catalysis of palladium (0) and a chiral organocatalyst …

Abstract A dirhodium carboxylate catalyzed [1+ 1+ 3] annulation reaction of diazoenals and
vinyl azides that gives synthetically important enal‐functionalized 1‐pyrroline derivatives …

Lewis acid-mediated conjugate addition of vinyl azides to electron-deficient alkenes led to
the efficient construction of 1-pyrroline skeletons. The reactions of vinyl azides with 3 …

Diastereoselective reactions supported by metals and nonmetals offer a multifaceted path
for the synthesis of robust intermediates of value to academia and industry. The reactions …

An atom-economical method for accessing tetrasubstituted 4, 5-biscarbonylimidazoles by
reaction between glycine derivatives and 5-alkoxyoxazoles is reported. The method, which …

The mechanism‐oriented reaction design for the divergent synthesis of chiral molecules
from simple starting materials is highly desirable. In this work, aromatic amide‐derived …