Recent Advances in the Direct Synthesis of H2O2

RJ Lewis, GJ Hutchings - ChemCatChem, 2019 - Wiley Online Library
Abstract Hydrogen peroxide (H2O2) is a highly effective, green oxidant that has found
application in sectors ranging from the synthesis of fine chemicals and waste stream …

[HTML][HTML] Recent advances in the direct synthesis of hydrogen peroxide using chemical catalysis—A review

S Ranganathan, V Sieber - Catalysts, 2018 - mdpi.com
Hydrogen peroxide is an important chemical of increasing demand in today's world.
Currently, the anthraquinone autoxidation process dominates the industrial production of …

[HTML][HTML] High activity and selectivity of single palladium atom for oxygen hydrogenation to H2O2

S Yu, X Cheng, Y Wang, B Xiao, Y Xing, J Ren… - Nature …, 2022 - nature.com
Nanosized palladium (Pd)-based catalysts are widely used in the direct hydrogen peroxide
(H2O2) synthesis from H2 and O2, while its selectivity and yield remain inferior because of …

N-heterocyclic carbene modified palladium catalysts for the direct synthesis of hydrogen peroxide

RJ Lewis, M Koy, M Macino, M Das… - Journal of the …, 2022 - ACS Publications
Heterogeneous palladium catalysts modified by N-heterocyclic carbenes (NHCs) are shown
to be highly effective toward the direct synthesis of hydrogen peroxide (H2O2), in the …

Tandem catalysis for selective oxidation of methane to oxygenates using oxygen over PdCu/zeolite

B Wu, T Lin, M Huang, S Li, J Li, X Yu… - Angewandte Chemie …, 2022 - Wiley Online Library
Selective oxidation of methane to oxygenates with O2 under mild conditions remains a great
challenge. Here we report a ZSM‐5 (Z‐5) supported PdCu bimetallic catalyst (PdCu/Z‐5) for …

On the Reaction Mechanism of Direct H2O2 Formation over Pd Catalysts

L Chen, JW Medlin, H Gronbeck - ACS Catalysis, 2021 - ACS Publications
Hydrogen peroxide (H2O2) is an effective green oxidant, which is used in many industrial
processes. Here, the reaction mechanism for direct formation of H2O2 from H2 and O2 over …

Highly Efficient H2O2 Production via Two-Electron Electrochemical Oxygen Reduction over Fe-Doped CeO2

X Mei, X Zhao, Y Chen, B Deng, Q Geng… - ACS Sustainable …, 2023 - ACS Publications
Electrochemical two-electron oxygen reduction reaction (2e-ORR) is regarded as a green
replacement to traditional anthraquinone processes for the continuous on-site production of …

Isolated Pd sites as selective catalysts for electrochemical and direct hydrogen peroxide synthesis

M Ledendecker, E Pizzutilo, G Malta, GV Fortunato… - ACS …, 2020 - ACS Publications
Palladium nanoparticles have been studied extensively as catalysts for the direct synthesis
of hydrogen peroxide, where selectivity remains a key challenge. Alloying Pd with other …

Microkinetic Modeling with Size-Dependent and Adsorbate–Adsorbate Interactions for the Direct Synthesis of H2O2 over Pd Nanoparticles

J Zhao, Z Yao, RJ Bunting, P Hu, J Wang - ACS Catalysis, 2023 - ACS Publications
As a bottleneck in the direct synthesis of hydrogen peroxide, the development of an efficient
palladium-based catalyst has garnered great attention. However, elusive active centers and …

[HTML][HTML] Cyclohexanone ammoximation via in situ H 2 O 2 production using TS-1 supported catalysts

RJ Lewis, K Ueura, Y Fukuta, TE Davies, DJ Morgan… - Green …, 2022 - pubs.rsc.org
The ammoximation of cyclohexanone to the corresponding oxime via in situ H2O2 formation
offers an attractive alternative to the current industrial means of production, overcoming the …