Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Multiblock copolymer synthesis via RAFT emulsion polymerization

GKK Clothier, TR Guimarães, SW Thompson… - Chemical Society …, 2023 - pubs.rsc.org
A multiblock copolymer is a polymer of a specific structure that consists of multiple covalently
linked segments, each comprising a different monomer type. The control of the monomer …

The block copolymer shuffle in size exclusion chromatography: the intrinsic problem with using elugrams to determine chain extension success

K Philipps, T Junkers, JJ Michels - Polymer Chemistry, 2021 - pubs.rsc.org
Size exclusion chromatography (SEC) based on direct homopolymer calibration is the
preferred method for molecular weight determination in macromolecular synthesis …

End-functionalized polymers by controlled/living radical polymerizations: synthesis and applications

D Zhou, LW Zhu, BH Wu, ZK Xu, LS Wan - Polymer Chemistry, 2022 - pubs.rsc.org
The precise design of polymers with well-defined end functionality has received great
interest for synthesizing polymeric materials with advanced or distinctive properties. In the …

Polymer synthesis with more than one form of living polymerization method

X Guo, B Choi, A Feng… - Macromolecular rapid …, 2018 - Wiley Online Library
Controlled radical polymerization (CRP) or controlled/living radical polymerization has
revolutionized the polymer industry as a tool for the preparation of a wide variety of …

Opportunities for dual RDRP agents in synthesizing novel polymeric materials

S Pearson, C St Thomas, R Guerrero-Santos… - Polymer …, 2017 - pubs.rsc.org
Combining reversible-deactivation radical polymerization (RDRP) techniques in a single
system provides access to exciting new polymeric materials which would be difficult to …

Trithiocarbonates in RAFT polymerization

G Moad - RAFT Polymerization: Methods, Synthesis and …, 2021 - Wiley Online Library
This chapter provides a review of the synthesis, reactions, and applications of
trithiocarbonates, R′ SC ( S) SR, in radical polymerization with reversible addition …

Combined nitroxide mediated radical polymerization techniques for block copolymer synthesis

A Kermagoret, D Gigmes - Tetrahedron, 2016 - Elsevier
Nitroxide mediated radical polymerization (NMP) is one of the most powerful method for
advanced polymer synthesis. However, NMP suffers from some limitations, in particular to …

Alkoxyamine-functionalized latex nanoparticles through RAFT polymerization-induced self-assembly in water

C St Thomas, R Guerrero-Santos, F d'Agosto - Polymer Chemistry, 2015 - pubs.rsc.org
The use of a new symmetrical trithiocarbonate holding two alkoxyamine moieties (I), was
explored in surfactant-free emulsion polymerization of styrene or n-butyl acrylate through …

Thickening behavior of thermo‐associative water soluble multiblock copolymers under redox RAFT polymerization

H Maldonado‐Textle… - Polymer Engineering …, 2022 - Wiley Online Library
In this study, the synthesis of thermo‐associative water soluble multiblock copolymers is
reported. A trithiocarbonate functionalized polyacrylamide (PAM) was prepared and …