Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Covalent on-surface polymerization

L Grill, S Hecht - Nature Chemistry, 2020 - nature.com
With the rapid development of scanning probe microscopy, it has become possible to study
polymerization processes on suitable surfaces at the atomic level and in real space. In the …

On-surface synthesis of a doubly anti-aromatic carbon allotrope

Y Gao, F Albrecht, I Rončević, I Ettedgui, P Kumar… - Nature, 2023 - nature.com
Synthetic carbon allotropes such as graphene, carbon nanotubes and fullerenes have
revolutionized materials science and led to new technologies. Many hypothetical carbon …

An sp-hybridized molecular carbon allotrope, cyclo [18] carbon

K Kaiser, LM Scriven, F Schulz, P Gawel, L Gross… - Science, 2019 - science.org
Carbon allotropes built from rings of two-coordinate atoms, known as cyclo [n] carbons, have
fascinated chemists for many years, but until now they could not be isolated or structurally …

Quantum nanomagnets in on-surface metal-free porphyrin chains

Y Zhao, K Jiang, C Li, Y Liu, G Zhu, M Pizzochero… - Nature Chemistry, 2023 - nature.com
Unlike classic spins, quantum magnets are spin systems that interact via the exchange
interaction and exhibit collective quantum behaviours, such as fractional excitations …

On-surface synthesis of aromatic cyclo [10] carbon and cyclo [14] carbon

L Sun, W Zheng, W Gao, F Kang, M Zhao, W Xu - Nature, 2023 - nature.com
All-carbon materials based on sp 2-hybridized atoms, such as fullerenes, carbon nanotubes
and graphene, have been much explored due to their remarkable physicochemical …

Nanoarchitectonics beyond self‐assembly: challenges to create bio‐like hierarchic organization

K Ariga, X Jia, J Song, JP Hill… - Angewandte Chemie …, 2020 - Wiley Online Library
Incorporation of non‐equilibrium actions in the sequence of self‐assembly processes would
be an effective means to establish bio‐like high functionality hierarchical assemblies. As a …

Selectivity in single-molecule reactions by tip-induced redox chemistry

F Albrecht, S Fatayer, I Pozo, I Tavernelli, J Repp… - Science, 2022 - science.org
Controlling selectivity of reactions is an ongoing quest in chemistry. In this work, we
demonstrate reversible and selective bond formation and dissociation promoted by tip …

Plasmonic optical tweezers for particle manipulation: principles, methods, and applications

Y Ren, Q Chen, M He, X Zhang, H Qi, Y Yan - ACS nano, 2021 - ACS Publications
Inspired by the idea of combining conventional optical tweezers with plasmonic
nanostructures, a technique named plasmonic optical tweezers (POT) has been widely …

Cyclo [18] carbon: Insight into electronic structure, aromaticity, and surface coupling

GV Baryshnikov, RR Valiev, AV Kuklin… - The journal of …, 2019 - ACS Publications
Cyclo [18] carbon (C18) is studied computationally at the density functional theory (DFT) and
ab initio levels to obtain insight into its electronic structure, aromaticity, and adsorption …