Recent developments in the preparation and chemistry of metallacycles and metallacages via coordination

TR Cook, PJ Stang - Chemical reviews, 2015 - ACS Publications
The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

[HTML][HTML] Recent developments of supramolecular metal-based structures for applications in cancer therapy and imaging

A Pöthig, A Casini - Theranostics, 2019 - ncbi.nlm.nih.gov
The biomedical application of discrete supramolecular metal-based structures, including
supramolecular coordination complexes (SCCs), is still an emergent field of study. However …

Polyaromatic N-heterocyclic carbene ligands and π-stacking. Catalytic consequences

E Peris - Chemical Communications, 2016 - pubs.rsc.org
In the course of our most recent research, we demonstrated how homogeneous catalysts
with polyaromatic functionalities possess properties that clearly differ from those shown by …

Rhenium‐Carbonyl‐Based Supramolecular Coordination Complexes: Synthesis, Structure and Properties

D Gupta, M Sathiyendiran - ChemistrySelect, 2018 - Wiley Online Library
Abstract The facial‐Re (CO) 3 core based supramolecular coordination complexes
represent a unique class of functional 2D and 3D metallacycles possessing advantages …

Experimental and Theoretical Approaches to the Influence of the Addition of Pyrene to a Series of Pd and Ni NHC‐Based Complexes: Catalytic Consequences

H Valdés, M Poyatos, G Ujaque… - Chemistry–A European …, 2015 - Wiley Online Library
A series of Ni and Pd complexes with three different N‐heterocyclic carbene (NHC)‐based
ligands (imidazolylidene, benzimidazolylidene and pyrene–imidazolylidene) has been …

Self-assembly of oxamidato bridged ester functionalised dirhenium metallastirrups: synthesis, characterisation and cytotoxicity studies

B Ramakrishna, R Nagarajaprakash, V Veena… - Dalton …, 2015 - pubs.rsc.org
A new set of ester functionalised Re (I)-based oxamidato bridged neutral dinuclear
metallacycles were synthesised by self-assembly of four components from three building …

Single-pot self-assembly of heteroleptic Mn (I)-based aminoquinonato-bridged ester/amide-functionalized dinuclear metallastirrups: potential anticancer and visible …

D Divya, R Nagarajaprakash, P Vidhyapriya… - ACS …, 2019 - ACS Publications
Multicomponent self-assembly of Mn2 (CO) 10, a bis-chelating aminoquinonato (ON∩ ON)
bridge (L), and an ester/amide-functionalized flexible neutral ditopic linker (L′) has resulted …

Self-Assembled Manganese (I)-Based Selenolato-Bridged Tetranuclear Metallorectangles: Host–Guest Interaction, Anticancer, and CO-Releasing Studies

U Kumar, B Ramakrishna, J Varghese… - Inorganic …, 2021 - ACS Publications
Supramolecular one-step self-assembly of dimanganese decacarbonyl, diaryl diselenide,
and linear dipyridyl ligands (L= pyrazine (pz), 4, 4′-bipyridine (bpy), and trans-1, 2-bis (4 …

Visible and Near‐IR Emissions from k2N‐ and k3N‐Terpyridine Rhenium(I) Assemblies Obtained by an [n×1] Head‐to‐Tail Bonding Strategy

B Laramée‐Milette, N Zaccheroni… - … A European Journal, 2017 - Wiley Online Library
Abstract An [n× 1] head‐to‐tail bonding strategy has been used for the synthesis of ReI
metallacycles. From a k3N‐dicarbonyl precursor, a single discrete [4× 1] square assembly …

One-pot reaction of amide functionalized Re (I) based dinuclear metallacycles: Synthesis, characterization and evaluation for anticancer potential

R Govindarajan, R Nagarajaprakash, V Veena… - Polyhedron, 2018 - Elsevier
A series of self-assembled dinuclear metallacycles featuring fac-Re (CO) 3 core as metal
corners have been prepared in a facile one-pot reaction via a coordination driven self …