Time-resolved photoelectron spectroscopy: the continuing evolution of a mature technique

MS Schuurman, V Blanchet - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
Time-resolved photoelectron spectroscopy (TRPES) has become one of the most
widespread techniques for probing nonadiabatic dynamics in the excited electronic states of …

Ultrafast X-ray probes of elementary molecular events

D Keefer, SM Cavaletto, JR Rouxel… - Annual Review of …, 2023 - annualreviews.org
Elementary events that determine photochemical outcomes and molecular functionalities
happen on the femtosecond and subfemtosecond timescales. Among the most ubiquitous …

Conical intersection passages of molecules probed by X-ray diffraction and stimulated Raman spectroscopy

Y Nam, D Keefer, A Nenov, I Conti… - The Journal of …, 2021 - ACS Publications
Conical intersections (CoIns) play an important role in ultrafast relaxation channels. Their
monitoring remains a formidable experimental challenge. We theoretically compare the …

Formation of electronic coherences in conical intersection-mediated dynamics

SP Neville, A Stolow… - Journal of Physics B …, 2022 - iopscience.iop.org
We consider the formation of vibrationally-induced transient electronic coherences driven by
conical intersection (CI)-mediated population transfer between two electronic states. By …

Monitoring molecular vibronic coherences in a bichromophoric molecule by ultrafast X-ray spectroscopy

D Keefer, VM Freixas, H Song, S Tretiak… - Chemical …, 2021 - pubs.rsc.org
The role of quantum-mechanical coherences in the elementary photophysics of functional
optoelectronic molecular materials is currently under active study. Designing and controlling …

Coherent electronic-vibrational dynamics in deuterium bromide probed via attosecond transient-absorption spectroscopy

Y Kobayashi, KF Chang, SM Poullain, V Scutelnic… - Physical Review A, 2020 - APS
Ultrafast laser excitation can trigger complex coherent dynamics in molecules. Here, we
report attosecond transient-absorption experiments addressing simultaneous probing of …

Trends in angle-resolved molecular photoelectron spectroscopy

D Dowek, P Decleva - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The field of angle-resolved molecular photoelectron spectroscopy is reviewed, with
emphasis on foundations and most recent applications in different regimes of light–matter …

Towards molecular frame photoelectron angular distributions in polyatomic molecules from lab frame coherent rotational wavepacket evolution

M Gregory, P Hockett, A Stolow… - Journal of Physics B …, 2021 - iopscience.iop.org
A theory and method for a matrix-based reconstruction of molecular frame (MF)
photoelectron angular distributions (MFPADs) from laboratory frame (LF) measurements …

Ultrafast molecular frame quantum tomography

L Morrigan, SP Neville, M Gregory, AE Boguslavskiy… - Physical review …, 2023 - APS
We develop and experimentally demonstrate a methodology for a full molecular frame
quantum tomography (MFQT) of dynamical polyatomic systems. We exemplify this approach …

Resolving multiphoton processes with high-order anisotropy ultrafast X-ray scattering

A Natan, A Schori, G Owolabi, JP Cryan… - Faraday …, 2021 - pubs.rsc.org
We present the first results on experimentally measured ultrafast X-ray scattering of strongly
driven molecular iodine and analysis of high-order anisotropic components of the scattering …