Multiscale CO2 Electrocatalysis to C2+ Products: Reaction Mechanisms, Catalyst Design, and Device Fabrication

T Yan, X Chen, L Kumari, J Lin, M Li, Q Fan… - Chemical …, 2023 - ACS Publications
Electrosynthesis of value-added chemicals, directly from CO2, could foster achievement of
carbon neutral through an alternative electrical approach to the energy-intensive …

Enrichment of reactants and intermediates for electrocatalytic CO 2 reduction

PP Yang, MR Gao - Chemical Society Reviews, 2023 - pubs.rsc.org
The electrocatalytic carbon dioxide reduction reaction (CO2RR) presents a sustainable
route to convert renewable electricity to value-added fuels and feedstocks in the form of …

Surface passivation for highly active, selective, stable, and scalable CO2 electroreduction

J Zhu, J Li, R Lu, R Yu, S Zhao, C Li, L Lv, L Xia… - Nature …, 2023 - nature.com
Electrochemical conversion of CO2 to formic acid using Bismuth catalysts is one the most
promising pathways for industrialization. However, it is still difficult to achieve high formic …

Superaerophilic/superaerophobic cooperative electrode for efficient hydrogen evolution reaction via enhanced mass transfer

C Zhang, Z Xu, N Han, Y Tian, T Kallio, C Yu… - Science …, 2023 - science.org
Hydrogen evolution reaction (HER), as an effective method to produce green hydrogen, is
greatly impeded by inefficient mass transfer, ie, bubble adhesion on electrode, bubble …

Gas diffusion electrodes and membranes for CO2 reduction electrolysers

EW Lees, BAW Mowbray, FGL Parlane… - Nature Reviews …, 2022 - nature.com
The CO2 reduction reaction (CO2RR) is a potential means of using renewable electricity to
synthesize commodity chemicals and fuels. The CO2RR can be performed at industrially …

Rational design of electrocatalytic carbon dioxide reduction for a zero-carbon network

L Li, X Li, Y Sun, Y Xie - Chemical Society Reviews, 2022 - pubs.rsc.org
Electrocatalytic CO2 reduction has attracted much attention for its potential application in
CO2 mitigation and fuel production. During the past two decades, the electrocatalytic …

Surface hydroxide promotes CO2 electrolysis to ethylene in acidic conditions

Y Cao, Z Chen, P Li, A Ozden, P Ou, W Ni… - Nature …, 2023 - nature.com
Performing CO2 reduction in acidic conditions enables high single-pass CO2 conversion
efficiency. However, a faster kinetics of the hydrogen evolution reaction compared to CO2 …

Construction of C–N bonds from small-molecule precursors through heterogeneous electrocatalysis

J Li, Y Zhang, K Kuruvinashetti… - Nature Reviews Chemistry, 2022 - nature.com
Energy-intensive thermochemical processes within chemical manufacturing are a major
contributor to global CO2 emissions. With the increasing push for sustainability, the scientific …

Tailored catalyst microenvironments for CO2 electroreduction to multicarbon products on copper using bilayer ionomer coatings

C Kim, JC Bui, X Luo, JK Cooper, A Kusoglu… - Nature Energy, 2021 - nature.com
Electrochemical carbon dioxide reduction (CO2R) provides a promising pathway for
sustainable generation of fuels and chemicals. Copper (Cu) electrocatalysts catalyse CO2R …

Hydrophobic, Ultrastable Cuδ+ for Robust CO2 Electroreduction to C2 Products at Ampere-Current Levels

M Fang, M Wang, Z Wang, Z Zhang… - Journal of the …, 2023 - ACS Publications
Copper (Cu) is the only known material that can efficiently electrocatalyze CO2 to value-
added multicarbon products. Owing to the instability of the Cuδ+ state and microscopic …