Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications
MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Stereoselective amino acid synthesis by synergistic photoredox-pyridoxal radical biocatalysis
Developing synthetically useful enzymatic reactions that are not known in biochemistry and
organic chemistry is an important challenge in biocatalysis. Through the synergistic merger …
organic chemistry is an important challenge in biocatalysis. Through the synergistic merger …
Synergistic dual transition metal catalysis
UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …
enable a reaction between two separately activated substrates, has unlocked a plethora of …
Organo/transition-metal combined catalysis rejuvenates both in asymmetric synthesis
DF Chen, LZ Gong - Journal of the American Chemical Society, 2022 - ACS Publications
Since its advent two decades ago, asymmetric organo/transition-metal combined catalysis
(AOMC), including cooperative catalysis and relay catalysis, has leveraged redistribution of …
(AOMC), including cooperative catalysis and relay catalysis, has leveraged redistribution of …
Main group redox catalysis of organopnictogens: vertical periodic trends and emerging opportunities in group 15
JM Lipshultz, G Li, AT Radosevich - Journal of the American …, 2021 - ACS Publications
A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …
Challenges and opportunities in multicatalysis
Multicatalysis is an emerging field targeting the development of efficient catalytic
transformations to quickly convert relatively simple starting materials into more complex …
transformations to quickly convert relatively simple starting materials into more complex …
Enantio-and diastereodivergent construction of 1, 3-nonadjacent stereocenters bearing axial and central chirality through synergistic Pd/Cu catalysis
J Zhang, X Huo, J Xiao, L Zhao, S Ma… - Journal of the American …, 2021 - ACS Publications
In contrast to the widely explored methods for the asymmetric synthesis of molecules
bearing a single stereocenter or adjacent stereocenters, the concurrent construction of 1, 3 …
bearing a single stereocenter or adjacent stereocenters, the concurrent construction of 1, 3 …
Metal–organic frameworks for heterogeneous basic catalysis
Great attention has been given to metal–organic frameworks (MOFs)-derived solid bases
because of their attractive structure and catalytic performance in various organic reactions …
because of their attractive structure and catalytic performance in various organic reactions …
Dispersion and steric effects on enantio-/diastereoselectivities in synergistic dual transition-metal catalysis
Comprehensive computational studies were carried out to explore the mechanisms of
enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of α, α …
enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of α, α …