(NHC) Ni (0)-Catalyzed Branched-Selective Alkene Hydrosilylation with Secondary and Tertiary Silanes
AS Chang, KE Kawamura, HS Henness… - ACS …, 2022 - ACS Publications
Hydrosilylation is a valuable approach for the construction of organosilanes, which are
precursors to silicone materials that are widely incorporated in our everyday lives. The …
precursors to silicone materials that are widely incorporated in our everyday lives. The …
Room‐Temperature ALD of Metal Oxide Thin Films by Energy‐Enhanced ALD
SE Potts, HB Profijt, R Roelofs… - Chemical Vapor …, 2013 - Wiley Online Library
Room‐temperature atomic layer deposition (RT‐ALD) processes are of interest for
applications using temperature‐sensitive substrates. Challenges with RT‐ALD arise when …
applications using temperature‐sensitive substrates. Challenges with RT‐ALD arise when …
The Influence of Silane Steric Bulk on the Formation and Dynamic Behavior of Silyl Palladium Hydrides
Silanes play a versatile role in catalytic transformations, acting as hydride sources,
transmetalation reagents, and starting materials in the synthesis of highly valued …
transmetalation reagents, and starting materials in the synthesis of highly valued …
The use of calcination as a cue for structure characterization of entrapped metallocene catalysts on hybrid organic–inorganic silicas
MA Ullmann, JHZ dos Santos - Journal of Sol-Gel Science and …, 2023 - Springer
Organic–inorganic hybrid one-layer systems, entrapping Cp2ZrCl2 were calcined to
investigate the silica pores after organic portion volatilization. The burning of catalyst …
investigate the silica pores after organic portion volatilization. The burning of catalyst …
Relative kinetic stability towards redox decomposition of cerium (IV) complexes with some organic compounds
OO Voskresenskaya, NA Skorik - Monatshefte für Chemie-Chemical …, 2020 - Springer
A comparative analysis is performed on the stability constants\upbeta _ 1yn β 1 yn and
intramolecular redox decomposition rate constants k_ n\;=\; 1 kn= 1 obtained for …
intramolecular redox decomposition rate constants k_ n\;=\; 1 kn= 1 obtained for …
A kinetic view of the mechanism of the grignard reaction with alkoxysilanes
A Ploom, A Tuulmets, D Panov… - Phosphorus, Sulfur, and …, 2015 - Taylor & Francis
The kinetics of the reaction of n-butyl-and isopropylmagnesium chloride with
alkyltriethoxysilanes (RSi (OEt) 3) in diethyl ether were determined. The rate constants …
alkyltriethoxysilanes (RSi (OEt) 3) in diethyl ether were determined. The rate constants …
ЭЛЕКТРОННЫЕ ЭФФЕКТЫ 2-АЗАСИЛАТРАН-3-ОНОВЫХ ГРУПП
НФ Лазарева, ИМ Лазарев - Журнал общей химии, 2013 - elibrary.ru
1-Фенил-2-азасилатран-3-оны изучены методом мультиядерной спектроскопии ЯМР. π-
Акцепторные свойства 2-азасилатран-3-оновых групп значительно ниже, а σ-донорные …
Акцепторные свойства 2-азасилатран-3-оновых групп значительно ниже, а σ-донорные …
Electronic effects of 2-azasilatran-3-one groups
NF Lazareva, IM Lazarev - Russian Journal of General Chemistry, 2013 - Springer
Phenyl-2-azasilatran-3-ones have been studied by multinuclear NMR spectroscopy. The π-
accepting ability of 2-azasilatran-3-one groups is substantially lower and their σ-donating …
accepting ability of 2-azasilatran-3-one groups is substantially lower and their σ-donating …