(NHC) Ni (0)-Catalyzed Branched-Selective Alkene Hydrosilylation with Secondary and Tertiary Silanes

AS Chang, KE Kawamura, HS Henness… - ACS …, 2022 - ACS Publications
Hydrosilylation is a valuable approach for the construction of organosilanes, which are
precursors to silicone materials that are widely incorporated in our everyday lives. The …

Room‐Temperature ALD of Metal Oxide Thin Films by Energy‐Enhanced ALD

SE Potts, HB Profijt, R Roelofs… - Chemical Vapor …, 2013 - Wiley Online Library
Room‐temperature atomic layer deposition (RT‐ALD) processes are of interest for
applications using temperature‐sensitive substrates. Challenges with RT‐ALD arise when …

The Influence of Silane Steric Bulk on the Formation and Dynamic Behavior of Silyl Palladium Hydrides

MR Hurst, AG Davis, AK Cook - Organometallics, 2022 - ACS Publications
Silanes play a versatile role in catalytic transformations, acting as hydride sources,
transmetalation reagents, and starting materials in the synthesis of highly valued …

The use of calcination as a cue for structure characterization of entrapped metallocene catalysts on hybrid organic–inorganic silicas

MA Ullmann, JHZ dos Santos - Journal of Sol-Gel Science and …, 2023 - Springer
Organic–inorganic hybrid one-layer systems, entrapping Cp2ZrCl2 were calcined to
investigate the silica pores after organic portion volatilization. The burning of catalyst …

Relative kinetic stability towards redox decomposition of cerium (IV) complexes with some organic compounds

OO Voskresenskaya, NA Skorik - Monatshefte für Chemie-Chemical …, 2020 - Springer
A comparative analysis is performed on the stability constants\upbeta _ 1yn β 1 yn and
intramolecular redox decomposition rate constants k_ n\;=\; 1 kn= 1 obtained for …

A kinetic view of the mechanism of the grignard reaction with alkoxysilanes

A Ploom, A Tuulmets, D Panov… - Phosphorus, Sulfur, and …, 2015 - Taylor & Francis
The kinetics of the reaction of n-butyl-and isopropylmagnesium chloride with
alkyltriethoxysilanes (RSi (OEt) 3) in diethyl ether were determined. The rate constants …

ЭЛЕКТРОННЫЕ ЭФФЕКТЫ 2-АЗАСИЛАТРАН-3-ОНОВЫХ ГРУПП

НФ Лазарева, ИМ Лазарев - Журнал общей химии, 2013 - elibrary.ru
1-Фенил-2-азасилатран-3-оны изучены методом мультиядерной спектроскопии ЯМР. π-
Акцепторные свойства 2-азасилатран-3-оновых групп значительно ниже, а σ-донорные …

Electronic effects of 2-azasilatran-3-one groups

NF Lazareva, IM Lazarev - Russian Journal of General Chemistry, 2013 - Springer
Phenyl-2-azasilatran-3-ones have been studied by multinuclear NMR spectroscopy. The π-
accepting ability of 2-azasilatran-3-one groups is substantially lower and their σ-donating …

[引用][C] Chair of Organic Chemistry 2008-2012