Various organic reactions, including important synthetic reactions involving C–C, C–N, and
C–O bond formation as well as reactions of biomolecules, are accelerated when the …

The striking finding that reaction acceleration occurs in confined‐volume solutions sets up
an apparent conundrum: Microdroplets formed by spray ionization can be used to monitor …

BACKGROUND One driving motivation in the development of point-of-care (POC)
diagnostics is to conveniently and immediately provide information upon which healthcare …

Mass spectrometry (MS) is widely regarded as the most sensitive and specific general
purpose analytical technique. More than a century has passed for MS since the ground …

The identification of new photocatalytic pathways expands our knowledge of chemical
reactivity and enables new environmentally friendly synthetic applications. However, the …

Ambient ionization techniques allow complex chemical samples to be analyzed in their
native state with minimal sample preparation. This brings the obvious advantages of …

Based on a study of competitive substituent effects in a Claisen–Schmidt reaction, interfacial
effects have been shown to play an important role in accelerated reactions that occur in thin …

Double-barrel wire-in-a-capillary electrospray emitters prepared from theta-glass capillaries
were used to mix solutions during the electrospray process. The relative flow rate of each …

Chemical reactions conducted in different media (liquid phase, gas phase, or surface) drive
developments of versatile techniques for the detection of intermediates and prediction of …

Noble metals can be ionized by electrochemical corrosion and transported by electrospray
ionization. Mass spectrometry (MS) showed solvated metal ions as the main ionic …