Developing electrochemical hydrogenation towards industrial application

JT Kleinhaus, J Wolf, K Pellumbi, L Wickert… - Chemical Society …, 2023 - pubs.rsc.org
Electrochemical hydrogenation reactions gained significant attention as a sustainable and
efficient alternative to conventional thermocatalytic hydrogenations. This tutorial review …

Fundamental aspects of alkyne semi-hydrogenation over heterogeneous catalysts

Z Wang, Q Luo, S Mao, C Wang, J Xiong, Z Chen… - Nano Research, 2022 - Springer
Alkyne semi-hydrogenation is extremely significant for the production of polymer-grade
ethylene and lots of fine chemicals in modern industry. Many efforts had been devoted to …

S-scheme heterojunction photocatalysts for CO2 reduction

L Wang, B Zhu, J Zhang, JB Ghasemi, M Mousavi, J Yu - Matter, 2022 - cell.com
Summary Step-scheme (S-scheme) heterojunctions have been widely applied in
photocatalytic CO 2 reduction because they facilitate the spatial separation of …

Converting copper sulfide to copper with surface sulfur for electrocatalytic alkyne semi-hydrogenation with water

Y Wu, C Liu, C Wang, Y Yu, Y Shi, B Zhang - Nature communications, 2021 - nature.com
Electrocatalytic alkyne semi-hydrogenation to alkenes with water as the hydrogen source
using a low-cost noble-metal-free catalyst is highly desirable but challenging because of …

Selective visible-light photocatalysis of acetylene to ethylene using a cobalt molecular catalyst and water as a proton source

F Arcudi, L Ðorđević, N Schweitzer, SI Stupp… - Nature …, 2022 - nature.com
The production of polymers from ethylene requires the ethylene feed to be sufficiently
purified of acetylene contaminant. Accomplishing this task by thermally hydrogenating …

Tripodal Pd metallenes mediated by Nb2C MXenes for boosting alkynes semihydrogenation

Z Wei, Z Zhao, C Qiu, S Huang, Z Yao, M Wang… - Nature …, 2023 - nature.com
Abstract 2D metallene nanomaterials have spurred considerable attention in heterogeneous
catalysis by virtue of sufficient unsaturated metal atoms, high specific surface area and …

Selenium vacancy promotes transfer semihydrogenation of alkynes from water electrolysis

Y Ling, Y Wu, C Wang, C Liu, S Lu, B Zhang - ACS Catalysis, 2021 - ACS Publications
Developing an efficient strategy for the highly selective transformation of alkynes to alkenes
over a cost-effective catalyst using a cheap and safe hydrogen donor under ambient …

Homogeneous Ni single-atom sites in the NiZn intermetallic nanostructure for efficient semihydrogenation of acetylene

H Zhou, H Fu, B Li, X Yan, Y Su, X Pan… - ACS Sustainable …, 2023 - ACS Publications
Catalytic semihydrogenation of acetylene is crucial for ethylene purification but still faces a
grand challenge in circumventing deep hydrogenation and oligomerization so far, especially …

Opportunities in the design of metal@ oxide core-shell nanoparticles

PCD Mendes, Y Song, W Ma, TZH Gani… - … in Physics: X, 2023 - Taylor & Francis
Nanoparticles composed of metallic cores encapsulated in oxide shells emerged in the last
decade as an attractive class of nanocomposite materials due to their high stability and …

Enriching Pt3 ensemble with isolated 3-fold hollow site by crystal-phase engineering of Pt3Fe single-nanoparticle for acetylene hydrogenation

D Zhou, G Zhang, Y Li, S Liu, S Han, Y Zhou… - Chemical Engineering …, 2023 - Elsevier
Tuning the crystal-phase of bimetallic particles enables a precise control of catalytically
active sites but is experimentally challenged by the averaging ensemble effects that are …