Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

The conversion of widely available carboxylic acids into versatile boronic esters would be
highly enabling for synthesis. We found that this transformation can be effected by …

Boron's unique position in the Periodic Table, that is, at the apex of the line separating
metals and nonmetals, makes it highly versatile in chemical reactions and applications …

The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …

Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …

This review is a guided tour along the activation modes and reactivity of B–B, B–Si, B–N, B–
S, B–Se and B–P reagents, in the absence of any transition metal complex. Here are …

Conspectus Transition metal-catalyzed carbonylation reactions represent a direct and atom-
economical approach to introduce oxygen functionality into organic compounds, with CO …

We report herein a simple, metal-and additive-free, photoinduced borylation of haloarenes,
including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids …