Fischer Carbene Complexes as Chemical Multitalents: The Incredible Range of Products from Carbenepentacarbonylmetal α,β‐Unsaturated Complexes
A de Meijere, H Schirmer… - Angewandte Chemie …, 2000 - Wiley Online Library
The metal carbene complexes, discovered by EO Fischer at the start of the 1960s and
carrying his name, have since proved themselves to be irreplaceable building blocks for …
carrying his name, have since proved themselves to be irreplaceable building blocks for …
Metal-ion mediated deoxygenation of sulfoxides
VY Kukushkin - Coordination chemistry reviews, 1995 - Elsevier
Over the past two decades, the deoxygenation (ie the reduction of the sulfinyl group) of free
sulfoxides, R2S O, has been extensively studied and described in a number of reviews …
sulfoxides, R2S O, has been extensively studied and described in a number of reviews …
(1-Alkynyl) carbene Complexes (= 1-Metalla-1-buten-3-ynes): Tools for Synthesis
R Aumann, H Nienaber - Advances in Organometallic Chemistry, 1997 - Elsevier
Publisher Summary This chapter focuses on the reactivity of (1-alkyny1) carbene complexes,
especially if a regio-and/or stereoselective formation of C, C-or C, X bonds is achieved that …
especially if a regio-and/or stereoselective formation of C, C-or C, X bonds is achieved that …
Fischer‐Carbenkomplexe als chemische Multitalente: die unglaubliche Produktpalette aus α, β‐ungesättigten Carbenpentacarbonylmetall‐Komplexen
A de Meijere, H Schirmer, M Duetsch - Angewandte Chemie, 2000 - Wiley Online Library
Abstract Die von EO Fischer Anfang der sechziger Jahre erstmals isolierten und nach ihm
benannten Carbenmetall‐Komplexe haben sich mittlerweile als unentbehrliche …
benannten Carbenmetall‐Komplexe haben sich mittlerweile als unentbehrliche …
Competitive Pathways in the Reaction of Lithium Oxy‐ortho‐quinodimethanes and Fischer Alkoxy Alkynyl Carbene Complexes: Synthesis of Highly Functionalised …
P García‐García, C Novillo… - … A European Journal, 2011 - Wiley Online Library
Up to four different outcomes have been found for the reaction between 1‐oxy‐ortho‐
quinodimethanes (oQDMs) and alkoxy alkynyl Fischer carbene complexes (FCCs). The …
quinodimethanes (oQDMs) and alkoxy alkynyl Fischer carbene complexes (FCCs). The …
Chemical Modification of the Metal−Carbene Appendage in New, Trimetallic Adducts of Fe2(CO)6(μ-EE') (E = S, Se and E' = Se, Te) and Alkynyl Fischer Carbene Complexes …
P Mathur, S Ghosh, A Sarkar… - …, 1997 - ACS Publications
From the room temperature reaction of the transition metal alkynyl Fischer carbene
complexes (CO) 5M C (OEt)(C⋮ CPh)(M= Cr, W) with the homochalcogenide compounds …
complexes (CO) 5M C (OEt)(C⋮ CPh)(M= Cr, W) with the homochalcogenide compounds …
Organic Syntheses via Transition Metal Complexes, 74[1] Novel Phosphonium Allenide and 2‐Phosphanylethenyl Carbene Chromium and Tungsten Complexes
R Aumann, B Jasper, M Läge, B Krebs - Chemische Berichte, 1994 - Wiley Online Library
Abstract Alkynylcarbene complexes (CO) 5M C (OEt)‐C≡ C R 1 (M= Cr, W; R= Ph, tBu,
SiMe3) readily add tertiary phosphanes PPhR2′ 4 (R′= Ph, Me) to form stable zwitterionic …
SiMe3) readily add tertiary phosphanes PPhR2′ 4 (R′= Ph, Me) to form stable zwitterionic …
Preparation of organometallic uracil-analogue Fischer carbene complexes: Comparative study of conventional heating vs microwave irradiation
A Artillo, G Della Sala, M De Santis, A Llordes… - Journal of …, 2007 - Elsevier
Mono and disubstituted ureas react with alkynyl Fischer carbene complexes to give mono
and di N, N-substituted organometallic uracil analogues. An optimization of the process …
and di N, N-substituted organometallic uracil analogues. An optimization of the process …
[2+ 1] Carbenoid insertion reaction of Fischer carbene complexes with silanes: a synthesis of allylsilanes
CC Mak, MK Tse, KS Chan - The Journal of Organic Chemistry, 1994 - ACS Publications
Fischer carbene complexes havebeen shown to be versatile synthetic reagents in organic
synthesis in promoting cycloaddition reactions and metal-mediated reactions. 1 One aspect …
synthesis in promoting cycloaddition reactions and metal-mediated reactions. 1 One aspect …
The Pauson− Khand Reaction on Enynes Bearing a Pentacarbonylmetal (Cr, W) Carbene Tether
L Jordi, S Ricart, JM Viñas, JM Moretó - Organometallics, 1997 - ACS Publications
The study of the scope of the Pauson− Khand reaction on alkynyl (allylamino) carbene
pentacarbonyl complexes of chromium and tungsten (0) is reported. This reaction affords …
pentacarbonyl complexes of chromium and tungsten (0) is reported. This reaction affords …