C–H functionalization is a very active research field that has attracted the interest of
scientists from many disciplines. This Outlook describes the collaborative efforts within the …

Catalyst-controlled C–H functionalization by means of the C–H insertion chemistry of
rhodium carbenes has become a powerful synthetic method. The key requirements for the …

Carbon has the unique ability to bind four atoms and form stable tetravalent structures that
are prevalent in nature. The lack of one or two valences leads to a set of species …

A highly efficient catalytic method has been developed for asymmetric radical
cyclopropanation of alkenes with in situ-generated α-heteroaryldiazomethanes via Co (II) …

Heterobimetallic bismuth–rhodium paddlewheel complexes with phenylglycine ligands
carrying TIPS-groups at the meta-positions of the aromatic ring exhibit outstanding levels of …

A new chiral dirhodium tetracarboxylate catalyst, Rh2 (S-2-Cl-5-BrTPCP) 4, has been
developed for C–H functionalization reactions by means of donor/acceptor carbene …

At what became one of the most famous speeches in his career, in 1962, US President John
F. Kennedy issued a challenge to his nation to do what would be considered near …

Palladium-catalyzed cross-coupling reactions have gained a continuously growing interest
of synthetic organic chemists. The present review gives a brief account of applications of the …

This study describes general methods for the enantioselective syntheses of
pharmaceutically relevant 1-aryl-2-heteroaryl-and 1, 2-diheteroarylcyclopropane-1 …

Aryl-ester acylhydrazones readily react with phenyl iododiacetate (PIDA) in methanol to
produce the corresponding α-diazoesters with good to excellent yields (30 examples). The …