Transition metal nitroprussides: Crystal and electronic structure, and related properties
This review summarizes the state of the art on the structural features, thermal and
environmental stability, physical properties and potential applications of transition metal …
environmental stability, physical properties and potential applications of transition metal …
Adsorption of Aromatic Molecules in a Microporous Spin Crossover Material, Fe(pyrazine)[Fe(CN)5NO]. Tuning of Its Physical Properties
In microporous materials, the guest species interacts with the host framework and can
modify the electronic structure of that last one and the related physical and functional …
modify the electronic structure of that last one and the related physical and functional …
Spin-crossover in the Fe (4X-pyridine) 2 [Fe (CN) 5 NO] series with X= Cl, Br, and I. Role of the distortion for the iron atom coordination environment
This contribution reports the thermally induced spin crossover (SCO) in the titled series of
hybrid solids from the magnetic (SQUID), DSC, IR, Raman, and Mössbauer data. The onset …
hybrid solids from the magnetic (SQUID), DSC, IR, Raman, and Mössbauer data. The onset …
Thermally-induced spin transition in Fe (4, 4′-Azopyridine)[Fe (CN) 5NO]
Abstract The 4, 4′-Azopyridine molecule was incorporated as a pillar between adjacent
layers of Fe [Fe (CN) 5 NO] through a precipitation reaction. According to the solved and …
layers of Fe [Fe (CN) 5 NO] through a precipitation reaction. According to the solved and …
Thermally induced spin-crossover in the Fe (3-ethynylpyridine) 2 [M (CN) 4] series with M= Ni, Pd, and Pt. The role of the electron density found at the CN 5σ orbital
A series of 2D coordination polymers show thermally induced spin-crossover where the
temperature for the spin transition, according to the SQUID magnetic data, follows the order …
temperature for the spin transition, according to the SQUID magnetic data, follows the order …
Effect of CS2 and CO2 adsorption on the thermally-induced spin crossover in ferrous nitroprussides. Nature of the guest-host interactions
Tuning physical and functional properties in porous solids by introducing guest species in
their framework is an attractive research area in functional materials. Such a possibility is …
their framework is an attractive research area in functional materials. Such a possibility is …
Spin crossover in Hofmann-like coordination polymers. Effect of the axial ligand substituent and its position
This contribution reports the preparation and thermally induced spin crossover (SCO) in the
Hofmann-like Fe (3-hydroxypyridine) 2 [M (CN) 4] series, where M= Ni, Pd, and Pt. These …
Hofmann-like Fe (3-hydroxypyridine) 2 [M (CN) 4] series, where M= Ni, Pd, and Pt. These …
Thermally-induced spin-crossover (SCO) in Fe (4-ethynylpyrdine) 2 [Fe (CN) 5 NO]. Why is the SCO observed in 2D ferrous nitroprussides despite the NO–NC …
Pillared ferrous nitroprussides form an interesting series of coordination polymers where the
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …
spin crossover (SCO) behavior has been observed for several pillar organic molecules. This …
Fe[4-(3-Phenylpropyl)Pyridine]2[Fe(CN)5NO]: A 2D Coordination Polymer with Thermally-Induced Spin Transition and Nature of Its Asymmetric Hysteresis Loop
The titled material crystallizes with an orthorhombic unit cell, in the P 21212 space group
(Nr. 18). Its crystal structure was solved and refined from powder XRD patterns. The solid …
(Nr. 18). Its crystal structure was solved and refined from powder XRD patterns. The solid …
Fe(L)2[M(CN)4] with L = 4-Ethyl Isonicotinate and M = Ni, Pd, Pt.─A Series of Hofmann-Type Frameworks with Spin Crossover: The Dominant Role of the Fe–NC …
This contribution reports the incorporation of an organic pillar (L), 4-ethyl isonicotinate,
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …
between adjacent layers of the series of 2D coordination polymers, Fe [M (CN) 4], with M …