Complexes of diamagnetic cations with radical anion ligands

IV Ershova, AV Piskunov… - Russian Chemical …, 2020 - iopscience.iop.org
Complexes of diamagnetic cations with radical anion ligands - IOPscience This site uses
cookies. By continuing to use this site you agree to our use of cookies. To find out more, see …

Spirocyclic nitroxides as versatile tools in modern natural sciences: from synthesis to applications. Part I. Old and new synthetic approaches to spirocyclic nitroxyl …

EV Zaytseva, DG Mazhukin - Molecules, 2021 - mdpi.com
Spirocyclic nitroxyl radicals (SNRs) are stable paramagnetics bearing spiro-junction at α-, β-,
or γ-carbon atom of the nitroxide fragment, which is part of the heterocyclic system. Despite …

Mesogenic behavior of a 6-oxoverdazyl diradical: towards organic high-spin liquid crystals

S Kapuściński, J Szczytko, D Pociecha… - Materials Chemistry …, 2024 - pubs.rsc.org
A mesogenic building block based on a 6-oxoverdazyl diradical possessing a robust triplet
ground state (ΔES–T= 1.06 (2) kcal mol− 1) has been developed. Its substitution with …

Discs, dumbbells and superdiscs: Molecular and supermolecular architecture dependent magnetic behavior of mesogenic Blatter radical derivatives

S Kapuściński, J Szczytko, D Pociecha… - Materials Chemistry …, 2021 - pubs.rsc.org
A series of isomeric supermolecular bi-and tri-radicals, in which “half disc” mesogens are
connected 1, 4-and 1, 3, 5-through benzene, respectively, are investigated for liquid …

Paramagnetic Liquid Crystals With Close π–π Packing: The Effect of Blatter Radical Planarization on Behavior of Bent‐Core Mesogens

M Cigl, D Pociecha, R Jakubowski… - … A European Journal, 2023 - Wiley Online Library
A new, 19 π‐delocalized electrons planar Blatter radical building block was developed and
used to obtain paramagnetic bent‐core liquid crystals. The mesogens were investigated by …

Liquid crystalline derivatives of heterocyclic radicals

P Kaszyński, S Kapuściński… - Advances in Heterocyclic …, 2019 - Elsevier
Rapid progress in liquid crystalline radicals witnessed during the past 15 years has been
driven largely by fundamental studies and investigation of structure–property relationships in …

Spin symmetry breaking: Superparamagnetic and spin glass-like behavior observed in rod-like liquid crystalline organic compounds contacting nitroxide radical spins

S Sato, Y Uchida, R Tamura - Symmetry, 2020 - mdpi.com
Liquid crystalline (LC) organic radicals were expected to show a novel non-linear magnetic
response to external magnetic and electric fields due to their coherent collective molecular …

Diradical hexacoordinated tin (IV) bis-o-iminobenzosemiquinonates: synthesis, structure and magnetic properties

AV Piskunov, IN Meshcheryakova… - Journal of Molecular …, 2019 - Elsevier
By the metal salt metathesis reaction between tin (IV) bis-o-iminobenzosemiquinonates
imSQ i− Pr 2 SnCl 2 (1) or imSQ Me 2 SnCl 2 (2)(where imSQ i-Pr–radical-anion of N-2, 6-di …

Supramolecular polymerization in liquid crystalline media: toward modular synthesis of multifunctional core–shell columnar liquid crystals

K Yano, T Hanebuchi, XJ Zhang, Y Itoh… - Journal of the …, 2019 - ACS Publications
Recently, we discovered a modular synthetic approach for constructing core–shell columnar
liquid crystals (LCs) by supramolecular polymerization in LC media. In the present work, we …

Magnetically Manipulable Ionic Liquid Crystals Incorporating Neutral Radical Moiety

Y Uchida, T Sakaguchi, S Oki, S Shimono… - …, 2022 - Wiley Online Library
With a view to fabricating a new remote input‐output system by applying functional ionic
liquid crystalline (ILC) materials, we have developed novel ILC compounds containing a …