Recent advances in the application of parahydrogen in catalysis and biochemistry
G Buntkowsky, F Theiss, J Lins, YA Miloslavina… - RSC …, 2022 - pubs.rsc.org
Nuclear Magnetic Resonance (NMR) spectroscopy and Magnetic Resonance Imaging (MRI)
are analytical and diagnostic tools that are essential for a very broad field of applications …
are analytical and diagnostic tools that are essential for a very broad field of applications …
SABRE: Chemical kinetics and spin dynamics of the formation of hyperpolarization
In this review, we present the physical principles of the SABRE (Signal Amplification By
Reversible Exchange) method. SABRE is a promising hyperpolarization technique that …
Reversible Exchange) method. SABRE is a promising hyperpolarization technique that …
Instrumentation for hydrogenative parahydrogen-based hyperpolarization techniques
AB Schmidt, CR Bowers, K Buckenmaier… - Analytical …, 2022 - ACS Publications
The unique properties of the entangled, antisymmetric nuclear spin state of dihydrogen,
parahydrogen (pH2), has intrigued physicists, chemists, and other scientists for almost a …
parahydrogen (pH2), has intrigued physicists, chemists, and other scientists for almost a …
Zintl cluster supported low coordinate Rh (i) centers for catalytic H/D exchange between H 2 and D 2
Ligand exchange reactions of [Rh (COD){η4-Ge9 (Hyp) 3}] with L-type nucleophiles such as
PMe3, PPh3, IMe4 (IMe4= 1, 3, 4, 5-tetramethylimidazol-2-ylidene) or [W (Cp) 2H2] result in …
PMe3, PPh3, IMe4 (IMe4= 1, 3, 4, 5-tetramethylimidazol-2-ylidene) or [W (Cp) 2H2] result in …
Anomalously Large Antiphase Signals from Hyperpolarized Orthohydrogen Using a MOF‐Based SABRE Catalyst
Abstract Hyperpolarized orthohydrogen (o‐H2) is a frequent product of parahydrogen‐
based hyperpolarization approaches like signal amplification by reversible exchange …
based hyperpolarization approaches like signal amplification by reversible exchange …
[PDF][PDF] Nuclear magnetic resonance spectroscopy
CD Ridge - 2022 - toc.library.ethz.ch
Resonance Spectroscopy Page 1 Nuclear Magnetic Resonance Spectroscopy An Introduction
to Principles, Applications, and Experimental Methods Joseph B. Lambert Trinity University …
to Principles, Applications, and Experimental Methods Joseph B. Lambert Trinity University …
Chemical exchange saturation transfer in chemical reactions: a mechanistic tool for NMR detection and characterization of transient intermediates
N Lokesh, A Seegerer, J Hioe… - Journal of the American …, 2018 - ACS Publications
The low sensitivity of NMR and transient key intermediates below detection limit are the
central problems studying reaction mechanisms by NMR. Sensitivity can be enhanced by …
central problems studying reaction mechanisms by NMR. Sensitivity can be enhanced by …
Indirect detection of short-lived hydride intermediates of iridium N-heterocyclic carbene complexes via chemical exchange saturation transfer spectroscopy
For the first time, chemical exchange saturation transfer (CEST) nuclear magnetic resonance
(NMR) is utilized to study short-lived hydride intermediates in the catalytic cycle of an …
(NMR) is utilized to study short-lived hydride intermediates in the catalytic cycle of an …
Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis
L Kaltschnee, AN Pravdivtsev, M Gehl, G Huang… - Nature Catalysis, 2024 - nature.com
Hydrogenases are widespread metalloenzymes used for the activation and production of
molecular hydrogen. Understanding the catalytic mechanism of hydrogenases can help to …
molecular hydrogen. Understanding the catalytic mechanism of hydrogenases can help to …
A highly versatile automatized setup for quantitative measurements of PHIP enhancements
AS Kiryutin, G Sauer, S Hadjiali… - Journal of Magnetic …, 2017 - Elsevier
The design and application of a versatile and inexpensive experimental extension to NMR
spectrometers is described that allows to carry out highly reproducible PHIP experiments …
spectrometers is described that allows to carry out highly reproducible PHIP experiments …