Neutral and cationic half‐sandwich arene d6 metal complexes containing pyridyl and pyrimidyl thiourea ligands with interesting bonding modes: Synthesis, structural …

S Adhikari, O Hussain, RM Phillips… - Applied …, 2018 - Wiley Online Library
The reaction of [(p‐cymene) RuCl2] 2 and [Cp* MCl2] 2 (M= Rh/Ir) with benzoyl (2‐pyrimidyl)
thiourea (L1) and benzoyl (4‐picolyl) thiourea (L2) led to the formation of cationic complexes …

Ru, Rh and Ir metal complexes of pyridyl chalcone derivatives: Their potent antibacterial activity, comparable cytotoxicity potency and selectivity to cisplatin

L Dkhar, V Banothu, E Pinder, RM Phillips, W Kaminsky… - Polyhedron, 2020 - Elsevier
Half sandwich ruthenium, rhodium and iridium complexes containing pyridyl chalcone
analogues (L1 and L2) are prepared by the reaction of [(arene) M (µ-Cl) Cl] 2 (arene …

Neutral and cationic half-sandwich arene ruthenium, Cp* Rh and Cp* Ir oximato and oxime complexes: Synthesis, structural, DFT and biological studies

S Adhikari, NR Palepu, D Sutradhar… - Journal of …, 2016 - Elsevier
The reaction of [(p-cymene) RuCl 2] 2 and [Cp* MCl 2] 2 (M= Rh/Ir) with chelating ligand 2-
pyridyl cyanoxime {pyC (CN) NOH} leads to the formation of neutral oximato complexes …

Half-sandwich d6 metal complexes comprising of 2-substituted-1, 8-napthyridine ligands with unexpected bonding modes: Synthesis, structural and anti-cancer …

S Adhikari, O Hussain, RM Phillips… - Journal of Organometallic …, 2018 - Elsevier
The Friedländer condensation reaction between 2-aminonicotinealdehyde and
acetophenone derivatives in presence of potassium hydroxide yielded 2-substituted-1, 8 …

Synthesis, structural and chemosensitivity studies of arene d6 metal complexes having N‐phenyl‐N´‐(pyridyl/pyrimidyl)thiourea derivatives

S Adhikari, O Hussain, RM Phillips… - Applied …, 2018 - Wiley Online Library
The d6 metal complexes of thiourea derivatives were synthesized to investigate its
cytotoxicity. Treatment of various N‐phenyl‐N´ pyridyl/pyrimidyl thiourea ligands with half …

Synthesis, structure and bonding modes of pyrazine based ligands of Cp* Rh and Cp* Ir complexes: The study of in-vitro cytotoxicity against human cell lines

A Lapasam, E Pinder, RM Phillips, W Kaminsky… - Journal of …, 2019 - Elsevier
The reaction of multidentate pyrazine based ligands was explored towards Cp* rhodium and
Cp* iridium precursors. Mononuclear and dinuclear complexes formed by the ratio-based …

In vitro biological evaluation of half-sandwich platinum-group metal complexes containing benzothiazole moiety

L Shadap, V Banothu, E Pinder… - Journal of …, 2020 - Taylor & Francis
Ligands containing benzothiazole moiety upon reaction with arene platinum group metal
precursors in dry methanol yielded cationic complexes 1–9 having N∩ N bonding mode …