Catalytic enantioselective aldol reactions

Y Yamashita, T Yasukawa, WJ Yoo… - Chemical Society …, 2018 - pubs.rsc.org
Recent developments in catalytic asymmetric aldol reactions have been summarized.
Enantioselective aldol reactions are important methods to synthesize β-hydroxy carbonyl …

Advances in glycoside and oligosaccharide synthesis

CJ Crawford, PH Seeberger - Chemical Society Reviews, 2023 - pubs.rsc.org
The structural complexity of glycans poses a serious challenge in the chemical synthesis of
glycosides, oligosaccharides and glycoconjugates. Glycan complexity, determined by …

Stereodivergence in asymmetric catalysis

S Krautwald, EM Carreira - Journal of the American Chemical …, 2017 - ACS Publications
This Perspective presents an overview of catalytic enantioselective transformations that
allow convenient access to all stereoisomers of a given product with multiple stereogenic …

Enantioselective chemo‐and biocatalysis: partners in retrosynthesis

M Hönig, P Sondermann, NJ Turner… - Angewandte Chemie …, 2017 - Wiley Online Library
Recent developments of stereoselective biocatalytic and chemocatalytic methods are
discussed. The review provides a guide to the use of biocatalytic methods in the area of …

Catalytic peptide assemblies

O Zozulia, MA Dolan, IV Korendovych - Chemical Society Reviews, 2018 - pubs.rsc.org
Self-assembly of molecules often results in new emerging properties. Even very short
peptides can self-assemble into structures with a variety of physical and structural …

Asymmetric enamine catalysis

S Mukherjee, JW Yang, S Hoffmann, B List - Chemical Reviews, 2007 - ACS Publications
The catalysis by primary and secondary amines of electrophilic substitution reactions in the
R-position of carbonyl compounds and related reactions via enamine intermediates is called …

Small-molecule H-bond donors in asymmetric catalysis

AG Doyle, EN Jacobsen - Chemical Reviews, 2007 - ACS Publications
Enantioselective synthesis with small-molecule chiral hydrogen-bond donors has emerged
as a frontier of research in the field of asymmetric catalysis. Organic chemists have …

The diarylprolinol silyl ethers: ten years after

BS Donslund, TK Johansen, PH Poulsen… - Angewandte Chemie …, 2015 - Wiley Online Library
Asymmetric organocatalysis has experienced an incredible development since the
beginning of this century. The expansion of the field has led to a large number of efficient …

Chiral Brønsted acid-catalyzed direct Mannich reactions via electrophilic activation

D Uraguchi, M Terada - Journal of the American Chemical Society, 2004 - ACS Publications
It was found that the phosphoric acid derivatives of general structure 1 serve as highly
effective catalysts for the direct addition of acetyl acetone to N-Boc-protected arylimines. The …

In the golden age of organocatalysis

PI Dalko, L Moisan - Angewandte Chemie International Edition, 2004 - Wiley Online Library
The term “organocatalysis” describes the acceleration of chemical reactions through the
addition of a substoichiometric quantity of an organic compound. The interest in this field has …