[HTML][HTML] Spin crossover in discrete polynuclear iron (II) complexes
Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …
a wide variety of potential applications, including as displays, sensors, actuators or memory …
[HTML][HTML] Spin crossover with thermal hysteresis: practicalities and lessons learnt
S Brooker - Chemical Society Reviews, 2015 - pubs.rsc.org
The observation of spin crossover with thermal hysteresis loops of more than a few Kelvin
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …
Spin crossover in iron (III) complexes
Spin crossover compounds are a diverse class of switchable materials with applications
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …
Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …
Enhanced activity and acid pH stability of Prussian blue-type oxygen evolution electrocatalysts processed by chemical etching
L Han, P Tang, Á Reyes-Carmona… - Journal of the …, 2016 - ACS Publications
The development of upscalable oxygen evolving electrocatalysts from earth-abundant
metals able to operate in neutral or acidic environments and low overpotentials remains a …
metals able to operate in neutral or acidic environments and low overpotentials remains a …
Guest programmable multistep spin crossover in a porous 2-D Hofmann-type material
MJ Murphy, KA Zenere, F Ragon… - Journal of the …, 2017 - ACS Publications
The spin crossover (SCO) phenomenon defines an elegant class of switchable materials
that can show cooperative transitions when long-range elastic interactions are present. Such …
that can show cooperative transitions when long-range elastic interactions are present. Such …
Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration
W Huang, X Ma, O Sato, D Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …
which many metal atoms and organic ligands are integrated to synergize their properties. As …
Spin-crossover compounds with wide thermal hysteresis
MA Halcrow - Chemistry Letters, 2014 - academic.oup.com
Spin-crossover compounds showing wide thermal hysteresis are surveyed, and the factors
underlying these properties are discussed. Hysteresis is promoted by large structural …
underlying these properties are discussed. Hysteresis is promoted by large structural …
Rhodamine 6G-labeled pyridyl aroylhydrazone Fe (II) complex exhibiting synergetic spin crossover and fluorescence
J Yuan, SQ Wu, MJ Liu, O Sato… - Journal of the American …, 2018 - ACS Publications
Here, we use a pyridinecarbaldehyde rhodamine 6G hydrazone ligand (L) to synthesize an
Fe (II) complex 1 for the search of new fluorescent-spin crossover (SCO) materials. Single …
Fe (II) complex 1 for the search of new fluorescent-spin crossover (SCO) materials. Single …
Unusual metal centres/coordination spheres in spin crossover compounds
J Olguín - Coordination Chemistry Reviews, 2020 - Elsevier
The most widely studied spin crossover (SCO) systems are those involving hexacoordinate
iron (II) complexes immerse in the “magic” N 6 coordination sphere. In this review the …
iron (II) complexes immerse in the “magic” N 6 coordination sphere. In this review the …