Combined solid-state NMR, FT-IR and computational studies on layered and porous materials

G Paul, C Bisio, I Braschi, M Cossi, G Gatti… - Chemical Society …, 2018 - pubs.rsc.org
Understanding the structure–property relationship of solids is of utmost relevance for
efficient chemical processes and technological applications in industries. This contribution …

Small molecules, non-covalent interactions, and confinement

G Buntkowsky, M Vogel - Molecules, 2020 - mdpi.com
This review gives an overview of current trends in the investigation of small guest molecules,
confined in neat and functionalized mesoporous silica materials by a combination of solid …

Recent developments in solid-state NMR spectroscopy of crystalline microporous materials

SE Ashbrook, DM Dawson, VR Seymour - … Chemistry Chemical Physics, 2014 - pubs.rsc.org
Microporous materials, having pores and channels on the same size scale as small to
medium molecules, have found many important applications in current technologies …

Recent advances in solid state NMR of small molecules in confinement

M Werner, N Rothermel, H Breitzke… - Israel Journal of …, 2014 - Wiley Online Library
In the past years, porous media have become a major focus of materials science, due to
their versatile properties, such as high surface area, low specific weight, high surface …

Translational and Rotational Dynamics of molecules confined in zeolite nanocages by means of deuteron NMR

ZT Lalowicz, A Birczyński… - The Journal of Physical …, 2017 - ACS Publications
The main aim of our approach is to gain a comprehensive view of mobility of small
molecules in confinement as reported by 2H NMR spectroscopy. The spectra and spin …

Deuteron spin–lattice relaxation in the presence of an activation energy distribution: Application to methanols in zeolite NaX

G Stoch, EE Ylinen, A Birczynski, ZT Lalowicz… - Solid State Nuclear …, 2013 - Elsevier
A new method is introduced for analyzing deuteron spin–lattice relaxation in molecular
systems with a broad distribution of activation energies and correlation times. In such …

Water confinement in faujasite cages: a deuteron NMR investigation in a wide temperature range. 2. Spectra and relaxation at high temperature

AM Szymocha, ZT Lalowicz, A Birczyński… - The Journal of …, 2014 - ACS Publications
Deuteron NMR spectra and spin–lattice relaxation were measured for D2O confined in NaX,
NaY, and DY faujasites with various loadings at temperatures ranging from 200 to 310 K …

High-temperature and high-pressure NMR investigations of low viscous fluids confined in mesoporous systems

S Ok, J Sheets, SA Welch, DR Cole… - Zeitschrift für …, 2021 - degruyter.com
In this contribution, the relaxation and diffusional behaviors of low viscous fluids, water and
methanol confined into mesoporous silica and controlled size pore glass were investigated …

Molecular dynamics of 4-cyano-3-fluorophenyl 4-butylbenzoate (4CFPB) glass-forming liquid crystal in unidirectional silicon nanopores

T Rozwadowski, M Massalska-Arodź, J Krawczyk… - Liquid …, 2014 - Taylor & Francis
Complex dynamics of 4-cyano-3-fluorophenyl 4-butylbenzoate (4CFPB) in cylindrical non-
intersecting nanopores, mean diameters 6 nm and 8 nm was studied by broadband …

Acetone–d6 mobility in confinement of D-ZSM-5 structure: A deuteron NMR study

A Birczyński, AM Szymocha, WP We… - Chemical Physics …, 2022 - Elsevier
There are two typical ranges of temperature observed in mobility of molecules in
confinement of eg. zeolite structure: translational mobility above TS, and localized molecules …