Synthesis of heterocyclic and carbocyclic compounds via alkynyl, allyl, and propargyl organometallics of cyclopentadienyl iron, molybdenum, and tungsten complexes

CL Li, RS Liu - Chemical Reviews, 2000 - ACS Publications
Chien-Le Li was born in Tainan City, Taiwan, in 1976. He received his B. Sc. degree in 1998
from National Tsing-Hua University and began its Ph. D program in 1999. He joined Dr. Liu's …

[图书][B] Asymmetric synthetic methodology

DJ Ager, MB East - 2020 - taylorfrancis.com
This comprehensive text presents a critical discussion of the scopes and limitations of
various organic synthetic methodologies that are available for performing asymmetric …

Hydrogen bonding in organometallic crystals—a survey

D Braga, F Grepioni, GR Desiraju - Journal of organometallic chemistry, 1997 - Elsevier
Patterns of hydrogen bonding in organometallic crystals and the relationship with the
hydrogen bonding patterns in organic solids have been discussed. It has been shown, inter …

Synthesis and Characterization of Stable Cationic [Hydrotris(1-pyrazolyl)borato]Mo(CO)(NO)(η3-allyl) ComplexesSolid-State and Solution Evidence for an η2-Allyl …

LA Villanueva, YD Ward, R Lachicotte… - …, 1996 - ACS Publications
From the corresponding TpMo (CO) 2 (π-allyl) complexes, four symmetrically substituted
TpMo (CO)(NO)(π-allyl)+ complexes (π-allyl= propenyl, 2-methylpropenyl, cyclohexenyl …

[PDF][PDF] Enantiocontrolled [5+ 2] Cycloaddition to η 3-Pyranylmolybdenum π-Complexes. Synthesis of Substituted Oxabicyclo [3.2. 1] octenes of High Enantiopurity

J Yin, LS Liebeskind - Journal of the American Chemical Society, 1999 - academia.edu
Consider the synthetic potential of enantiomerically pure, stoichiometric transition metal π-
complexes derived from an inexpensive metal source and from readily available chiral-pool …

Stereocontrolled Oxidative Addition of Zerovalent Molybdenum to Enantiomerically Pure Allylic Acetates with Either Inversion or Retention at the Stereogenic Center

YD Ward, LA Villanueva, GD Allred… - Journal of the …, 1996 - ACS Publications
In both the catalytic and stoichiometric manifold, allylic substitutions catalyzed by transition
metal complexes have contributed significantly to the library of transformations available to …

Orientational and Stereochemical Preferences in [Hydridotris(3,5-dimethyl-1-pyrazolyl)borato](CO)2W(η3-allyl) Complexes

DS Frohnapfel, PS White, JL Templeton… - …, 1997 - ACS Publications
Irradiation of Tp '(CO) 3WH in the presence of alkynes or unconjugated dienes generates η3-
allyl complexes, Tp '(CO) 2W (η3-CHRCHCHR '). A kinetic preference for anti-alkyl …

New oxidative demetalation protocol for molybdenum π-complexes: Enantiocontrolled synthesis of unsaturated ketones and lactones

A Alcudia, RG Arrayás… - The Journal of Organic …, 2002 - ACS Publications
An efficient and general oxidative demetalation of (η3-allyl) molybdenum complexes using
pyridinium dichromate allows the introduction of a carbonyl group at an allylic terminus of …

Utility of a Diene− Tricarbonyliron Complex as a Mobile Chiral Auxiliary: Regio-and Stereocontrolled Functionalization of Acyclic Diene Ligands

Y Takemoto, N Yoshikawa, Y Baba… - Journal of the …, 1999 - ACS Publications
Stereoselective construction of contiguous stereogenic centers of acyclic compounds by
using the Fe (CO) 3 moiety as a mobile chiral auxiliary is described. Although the reactions …

Hydrogen bonds in inorganic chemistry: application to crystal design

L Brammer - Crystal Design: Structure and Function, 2003 - Wiley Online Library
The foremost goal of crystal engineering [1] is to tailor the chemical and/or physical
properties of crystalline solids through crystal design at the molecular level. A detailed …