Metal complexes in the synthesis of biodegradable polymers: achievements and prospects

BN Mankaev, SS Karlov - Materials, 2023 - mdpi.com
This review describes recent advances in the synthesis of homopolymers of lactide and
related cyclic esters via ring-opening polymerization (ROP) in the presence of metal …

Cooperative Initiation in a Dinuclear Indium Complex for CO2 Epoxide Copolymerization

HJ Jung, K Nyamayaro, HA Baalbaki… - Inorganic …, 2023 - ACS Publications
Dinuclear indium complexes have been synthesized and characterized. These include
neutral and cationic indium complexes supported by a Schiff base ligand bearing a …

Group 13 salphen compounds (In, Ga and Al): a comparison of their structural features and activities as catalysts for cyclic carbonate synthesis

DJ Cabrera, RD Lewis, C Díez-Poza… - Dalton …, 2023 - pubs.rsc.org
Many complexes based on group 13 elements have been successfully applied as catalysts
for the synthesis of cyclic carbonates from epoxides and CO2 and to date these have …

Epoxide/CO2 Cycloaddition Reaction Catalyzed by Indium Chloride Complexes Supported by Constrained Inden Schiff‐Base Ligands

T Piyawongsiri, N Laiwattanapaisarn… - …, 2023 - Wiley Online Library
Cyclic carbonates have received significant interests for uses as reagents, solvents, and
monomers. The coupling reaction of epoxides with carbon dioxide (CO2) to produce cyclic …

Aluminium complexes of phenoxy-azo ligands in the catalysis of rac-lactide polymerisation

P Sumrit, S Kamavichanurat, W Joopor… - Dalton …, 2024 - pubs.rsc.org
Fourteen new phenoxy-azo aluminium complexes comprising two series, namely, dimethyl
{phenoxy-azo} aluminium complexes 1a–7a and monomethyl {phenoxy-azo} aluminium …

Hemilabile ligands supporting cationic indium complexes: tuning reactivity in catalysis

C Goonesinghe - 2023 - open.library.ubc.ca
Over the years, numerous neutral indium catalysts have been studied for polymerization
reactions. However, recent research conducted by Mehrkhodavandi and co-workers has …

Neutral and cationic indium complexes for the synthesis of functionalized monomers and polymers

HJ Jung - 2022 - open.library.ubc.ca
Many efforts have been made to develop sustainable polymers that are functional as well as
ultimately degradable in response to worldwide plastic pollution. Accordingly, these have …