The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …

Ligand-to-metal charge transfer (LMCT) excited states are capable of undergoing a wide
array of photochemical reactions, yet receive minimal attention compared to other charge …

Incorporation of fluoroalkyl motifs in pharmaceuticals can enhance the therapeutic profiles of
the parent molecules. The hydrofluoroalkylation of alkenes has emerged as a promising …

Cuproptosis is a novel copper‐dependent programmed cell death. The efficacy of
cuproptosis is highly dependent on intracellular copper accumulation and counteracted by a …

Unactivated olefins are converted to alkyl azides with bench-stable NaN3 in the presence of
FeCl3· 6H2O under blue-light irradiation. The products are obtained with anti-Markovnikov …

Reforming sustainable 3d-metal-based visible light catalytic platforms for inert bulk chemical
activation is highly desirable. Herein, we demonstrate the use of a Brønsted acid to unlock …

The synthesis of tertiary phosphines (III) has been a long-standing challenge in synthetic
chemistry because of inevitable issues including harsh conditions, sensitive organometallic …

A Cu-electrocatalytic azidation of N-aryl enamines and subsequent denitrogenative
annulation for the construction of quinoxaline frameworks is reported. Only 0.5 mol% of …

Herein, we report the rational design of a modular dual photoredox and cobalt catalysis
paradigm for the difunctionalization of unsaturated hydrocarbons, unlocking the synthesis of …

Abstract Efficient methods for synthesizing 1, 2‐aryl (alkenyl) heteroatomic cores,
encompassing heteroatoms such as nitrogen, oxygen, sulfur, and halogens, are of …